发明名称 METHOD FOR SYNTHESIS OF PHOSPHORYL-SUBSTITUTED 1,4-DICARBOXYLIC ACIDS
摘要 FIELD: chemistry. ^ SUBSTANCE: acid of general formula , where R can be a straight or branched alkyl, unsubstituted or substituted phenyl, where substitutes of the phenyl group may be 1-5 lower alkyl groups, 1-5 lower alkoxy groups, 1-5 halogen atoms, 1-5 dialkylamino groups, Y is a single bond or a methylene group, is obtained by mixing secondary phosphine oxides of formula R2P(O)H with unsaturated 1,4-dicarboxylic acids and then heating the mixture in a melt at normal pressure and temperature of 80-120C until completion of the reaction. ^ EFFECT: novel method of producing valuable intermediate products of organic synthesis. ^ 2 cl, 12 ex
申请公布号 RU2405789(C2) 申请公布日期 2010.12.10
申请号 RU20080129151 申请日期 2008.07.17
申请人 UCHREZHDENIE ROSSIJSKOJ AKADEMII NAUK INSTITUT FIZIOLOGICHESKI AKTIVNYKH VESHCHESTV RAN (IFAV RAN) 发明人 JARKEVICH ALLA NIKOLAEVNA;SAFRONOVA ZOJA VIKTOROVNA;PUSHIN ALEKSEJ NIKOLAEVICH;BACHURIN SERGEJ OLEGOVICH;ZEFIROV NIKOLAJ SERAFIMOVICH
分类号 C07F9/53 主分类号 C07F9/53
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