主权项 |
1. Formulation comprising one or more organic semiconducting compounds (OSC), and one or more organic solvents, wherein:
one or more organic semiconducting compound has a molecular weight of 2000 g/mol or less and is of the formula P6:wherein
n is an integer >1, R on each occurrence identically or differently denotes H, F, Cl, Br, I, CN, a straight-chain, branched or cyclic alkyl group having from 1 to 40 C atoms, in which one or more C atoms are optionally replaced by O, S, O—CO, CO—O, O—CO—O, CR0═CR0 or C≡C such that O— and/or S-atoms are not linked directly to each other, and in which one or more H atoms are optionally replaced by F, Cl, Br, I or CN, or denotes an aryl or heteroaryl group having from 4 to 20 ring atoms that is unsubstituted or substituted by one or more non-aromatic groups Rs, and wherein one or more groups R may also form a mono- or polycyclic aliphatic or aromatic ring system with one another and/or with the ring to which they are attached, Rs on each occurrence identically or differently denotes F, Cl, Br, I, CN, Sn(R00)3, Si(R00)3 or B(R00)2 a straight-chain, branched or cyclic alkyl group having from 1 to 25 C atoms, in which one or more C atoms are optionally replaced by O, S, O—CO, CO—O, O—CO—O, CR0═CR0, C≡C such that O—and/or S-atoms are not linked directly to each other, and in which one or more H atoms are optionally replaced by F, Cl, Br, I or CN, or Rs denotes an aryl or heteroaryl group having from 4 to 20 ring atoms that is unsubstituted or substituted by one or more non-aromatic groups Rs, and wherein one or more groups Rs may also form a ring system with one another and/or with R, R0 on each occurrence identically or differently denotes H, F, Cl, CN, alkyl having from 1 to 12 C atoms or aryl or heteroaryl having from 4 to 10 ring atoms, R00 on each occurrence identically or differently denotes H or an aliphatic or aromatic hydrocarbon group having from 1 to 20 C atoms, wherein two groups R00 may also form a ring together with the hetero atom (Sn, Si or B) to which they are attached, the formulation has a viscosity at 25° C. of less than 15 mPas and the boiling point of one or more organic solvent is at most 400° C. |