| 发明名称 |
METHOD FOR PRODUCING ESTER COMPOUND AND PALLADIUM CATALYST USED IN THE METHOD |
| 摘要 |
A method for producing an ester compound includes reacting a compound having at least one cyclic structure of a norbornene ring and a norbornadiene ring with an alcohol and carbon monoxide by using a palladium catalyst and an oxidizing agent, to thereby introduce ester groups to carbon atoms forming a double bond in the cyclic structure and obtaining the ester compound, wherein the palladium catalyst includes a palladium acetate having a nitrite ligand in an amount of 10% by mole or more in terms of metal, and the palladium acetate having a nitrite ligand is represented by the general formula (1): Pd3(CH3COO)5(NO2). |
| 申请公布号 |
US2015343432(A1) |
申请公布日期 |
2015.12.03 |
| 申请号 |
US201314431849 |
申请日期 |
2013.09.24 |
| 申请人 |
JX Nippon Oil & Energy Corporation |
发明人 |
KOMATSU Shinichi;SHIBASHI Akira;MATSUMOTO Takaya |
| 分类号 |
B01J31/22;C07C67/38 |
主分类号 |
B01J31/22 |
| 代理机构 |
|
代理人 |
|
| 主权项 |
1. A method for producing an ester compound, comprising reacting a compound having at least one cyclic structure of a norbornene ring and a norbornadiene ring with an alcohol and carbon monoxide by using a palladium catalyst and an oxidizing agent, to thereby introduce ester groups to carbon atoms forming a double bond in the cyclic structure and obtain the ester compound, wherein
the palladium catalyst comprises a palladium acetate having a nitrite ligand in an amount of 10% by mole or more in terms of metal, and the palladium acetate having a nitrite ligand is represented by the following general formula (1):
Pd3(CH3COO)5(NO2) (1). |
| 地址 |
Tokyo JP |
