发明名称 NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY AND METHOD OF MANUFACTURING THE SAME
摘要 A non-aqueous electrolyte secondary battery includes a positive electrode composite material layer containing first positive electrode active material particles containing a lithium nickel composite oxide, second positive electrode active material particles containing lithium iron phosphate, and a conductive material. A ratio of the second positive electrode active material particles in a total mass of the first positive electrode active material particles and the second positive electrode active material particles is not lower than 5 mass % and not higher than 20 mass %. A standard deviation σ representing distribution of an iron element satisfies a condition of 0.28≦σ≦0.52 when distribution of the iron element is determined by conducting area analysis with an electron probe microanalyzer in a cross-section of the positive electrode composite material layer.
申请公布号 US2015349329(A1) 申请公布日期 2015.12.03
申请号 US201514692844 申请日期 2015.04.22
申请人 TOYOTA JIDOSHA KABUSHIKI KAISHA 发明人 SAKA Hideyuki;FUJITA Hideaki;TAKAHASHI Keiichi;SANO Hideki;HASHIMOTO Tatsuya
分类号 H01M4/36;H01M10/0525;H01M4/04;H01M4/131;H01M4/1391 主分类号 H01M4/36
代理机构 代理人
主权项 1. A non-aqueous electrolyte secondary battery, comprising: a positive electrode composite material layer containing first positive electrode active material particles containing a lithium nickel composite oxide,second positive electrode active material particles containing lithium iron phosphate, anda conductive material, a ratio of said second positive electrode active material particles in a total mass of said first positive electrode active material particles and said second positive electrode active material particles being not lower than 5 mass % and not higher than 20 mass %, and a standard deviation σ satisfying a condition of 0.28≦σ≦0.52, which is calculated in the following expression (1)σ=1N∑i=1N(zi-1)2(1)when distribution of an iron element is determined by extracting a square measurement region of which one side has a length at least 0.5 time and at most 1.0 time as large as a thickness of said positive electrode composite material layer from a cross-section of said positive electrode composite material layer in parallel to a direction of thickness of said positive electrode composite material layer and conducting area analysis with an electron probe microanalyzer in said measurement region, where zi represents a value obtained by normalizing ΔIi by dividing said measurement region into N belt-shaped small regions Δyi (i=1, 2, . . . , N) in said direction of thickness and dividing a sum value ΔIi (i=1, 2, . . . , N) of iron element detection intensity at each measurement point included in one said small region Δyi by an average value I of ΔIi.
地址 Toyota-shi JP