主权项 |
1. A 1-Methyl-pyrazole(thio)indanyl carboxamide compound of formula (I) in which X1 represents CHF2; X2 represents hydrogen, halogen; cyano; nitro, hydroxyl, C1-C16-alkyl, C1-C6-haloalkyl having 1 to 9 identical or different halogen atoms; C3-C7-cycloalkyl, C3-C7-halocycloalkyl having 1 to 9 identical or different halogen atoms; C1-C6-alkoxy; C1-C6-haloalkoxy having 1 to 9 identical or different halogen atoms; C1-C6-alkylsulfanyl; C1-C6-haloalkylsulfanyl having 1 to 9 identical or different halogen atoms; C1-C6-alkylsulfonyl; or C1-C6-haloalkylsulfonyl having 1 to 9 identical or different halogen atoms; provided that in case that X2 represents hydrogen or methyl, then both R3 and R4 do not represent methyl and R1 and R2 do not represent either hydrogen or methyl; further provided that in case that X2 does not represents chlorine or fluorine; T represents an oxygen or sulfur atom; Q represents hydrogen, optionally substituted C1-C6-alkylsulfonyl; optionally substituted C1-C4-alkoxy-C1-C4-alkyl, or optionally substituted C1-C4-haloalkylsulfonyl; G represents halogen, nitro, cyano, C1-C12-alkyl; C1-C6-haloalkyl having 1 to 9 identical or different halogen atoms; C1-C6-alkoxy; C1-C6-haloalkoxy having 1 to 9 identical or different halogen atoms; C1-C6-alkylsulfanyl; C1-C6-haloalkylsulfanyl having 1 to 9 identical or different halogen atoms; C1-C6-alkylsulfonyl; C1-C6-haloalkylsulfonyl having 1 to 9 identical or different halogen atoms; C2-C12-alkenyl; C2-C12-alkynyl; C3-C7-cycloalkyl; phenyl; tri(C1-C8)alkylsilyl; or tri(C1-C8)alkylsilyl-C1-C8-alkyl; n represents 0, 1, 2 or 3 R1 represents hydrogen, halogen; cyano; C1-C16-alkyl; C1-C16-haloalkyl having 1 to 9 identical or different halogen atoms; C3-C8-cycloalkyl; C3-C7-halocycloalkyl having 1 to 9 identical or different halogen atoms; C1-C6-haloalkyl having 1 to 9 identical or different halogen atoms; (C3-C8-cycloalkyl)-C1-C8-alkyl; (C3-C8-cycloalkyl)-C3-C8-cycloalkyl; C2-C16-alkenyl; C2-C16-alkynyl; C2-C16-alkenyl-C1-C16-alkyl; C2-C16-alkynyl-C1-C16-alkyl; C1-C16-alkoxy; C3-C8-cycloalkyloxy; (C3-C8-cycloalkyl)-C1-C8-alkyloxy; C1-C8-alkylsulfanyl; C3-C8-cycloalkylsulfanyl; (C3-C8-cycloalkyl)-C1-C8-alkylsulfanyl; C2-C16-alkenyloxy; C3-C8-alkynyloxy; aryl-C1-C8-alkyloxy which is optionally substituted by up to 6 identical or different groups Rb; aryl-C1-C8-alkylsulfanyl which is optionally substituted by up to 6 identical or different groups Rb; aryloxy which is optionally substituted by up to 6 identical or different groups Rb; arylsulfanyl which is optionally substituted by up to 6 identical or different groups Rb; (C3-C8-cycloalkyl)-C2-C8-alkenyl; (C3-C8-cycloalkyl)-C2-C8-alkynyl; tri(C1-C8)alkylsilyl; tri(C1-C8)alkylsilyl-C1-C8-alkyl; aryl-C1-C8-alkyl which is optionally substituted by up to 6 identical or different groups Rb; aryl-C2-C8-alkenyl which is optionally substituted by up to 6 identical or different groups Rb; aryl-C2-C8-alkynyl which is optionally substituted by up to 6 identical or different groups Rb; C1-C8-alkylamino; di-C1-C8-alkylamino; arylamino which is optionally substituted by up to 6 identical or different groups Rb; C1-C8-alkylcarbonyl; C1-C8-alkylcarbonyloxy; C1-C8-alkylcarbonylamino; C1-C8-alkoxycarbonyl; C1-C8-alkyloxycarbonyloxy; C1-C8-alkylcarbamoyl; di-C1-C8-alkylcarbamoyl; C1-C8-alkylaminocarbonyloxy; di-C1-C8-alkylaminocarbonyloxy; N—(C1-C8-alkyl)hydroxycarbamoyl; C1-C8-alkoxycarbamoyl; N—(C1-C8-alkyl)-C1-C8-alkoxycarbamoyl; aryl-C1-C8-alkylamino which is optionally substituted by up to 6 identical or different groups Rb; (C1-C8-alkoxyimino)-C1-C8 alkyl; (C2-C8-cycloalkoxyimino)-C1-C8 alkyl; C1-C8-alkyliminoxy; C1-C8-alkyliminoxy-C1-C8-alkyl; each of which is optionally substituted; R2, R3 and R4 independently of one another represent hydrogen; halogen; cyano; hydroxyl; C1-C16-alkyl; C2-C16-haloalkyl having 1 to 9 identical or different halogen atoms; C3-C8-cycloalkyl; C3-C7-halocycloalkyl having 1 to 9 identical or different halogen atoms; C1-C6-haloalkyl having 1 to 9 identical or different halogen atoms; (C3-C8-cycloalkyl)-C1-C8-alkyl; (C3-C8-cycloalkyl)-C3-C8-cycloalkyl; C2-C16-alkenyl; C2-C16-alkynyl; C2-C16-alkenyl-C1-C16-alkyl; C2-C16-alkynyl-C1-C16-alkyl; C1-C16-alkoxy; C3-C8-cycloalkyloxy; (C3-C8-cycloalkyl)-C1-C8-alkyloxy; C1-C8-alkylsulfanyl; C3-C8-cycloalkylsulfanyl; (C3-C8-cycloalkyl)-C1-C8-alkylsulfanyl; C2-C16-alkenyloxy; C3-C8-alkynyloxy; aryl-C1-C8-alkyloxy which is optionally substituted by up to 6 identical or different groups Rb; aryl-C1-C8-alkylsulfanyl which is optionally substituted by up to 6 identical or different groups Rb; aryloxy which is optionally substituted by up to 6 identical or different groups Rb; arylsulfanyl which is optionally substituted by up to 6 identical or different groups Rb; (C3-C8-cycloalkyl)-C2-C8-alkenyl; (C3-C8-cycloalkyl)-C2-C8-alkynyl; tri(C1-C8)alkylsilyl; tri(C1-C8)alkylsilyl-C1-C8-alkyl; aryl-C1-C8-alkyl which is optionally substituted by up to 6 identical or different groups Rb; aryl-C2-C8-alkenyl which is optionally substituted by up to 6 identical or different groups Rb; aryl-C2-C8-alkynyl which is optionally substituted by up to 6 identical or different groups Rb; C1-C8-alkylamino; di-C1-C8-alkylamino; arylamino which is optionally substituted by up to 6 identical or different groups Rb; C1-C8-alkylcarbonyl; C1-C8-alkylcarbonyloxy; C1-C8-alkylcarbonylamino; C1-C8-alkoxycarbonyl; C1-C8-alkyloxycarbonyloxy; C1-C8-alkylcarbamoyl; di-C1-C8-alkylcarbamoyl; C1-C8-alkylaminocarbonyloxy; di-C1-C8-alkylaminocarbonyloxy; N—(C1-C8-alkyl)hydroxycarbamoyl; C1-C8-alkoxycarbamoyl; N—(C1-C8-alkyl)-C1-C8-alkoxycarbamoyl; aryl-C1-C8-alkylamino which is optionally substituted by up to 6 identical or different groups Rb; (C1-C8-alkoxyimino)-C1-C8-alkyl; (C2-C8-cycloalkoxyimino)-C1-C8-alkyl; C1-C8-alkyliminoxy; C1-C8-alkyliminoxy-C1-C8-alkyl; each of which is optionally substituted; R1and R2can form together with the carbon to which they are attached a C3-C8-cycloalkyl; C3-C8-cycloalkenyl, or a saturated 5, 6 or 7 membered heterocycle; each of which is optionally substituted; or may represent a group ═C(Y1)Y2 or a group ═N—O—Rc; R3 and R4 can form together with the carbon to which they are attached a C3-C8-cycloalkyl; C3-C8-cycloalkenyl, or a saturated 5, 6 or 7 membered heterocycle; each of which is optionally substituted; or may represent a group ═C(Y1)Y2 or a group ═N—O—Rc; Rb represents halogen; nitro, cyano, C1-C16-alkyl; C1-C6-haloalkyl having 1 to 9 identical or different halogen atoms; C1-C6-alkoxy; C1-C6-haloalkoxy having 1 to 9 identical or different halogen atoms; C1-C6-alkylsulfanyl; C1-C6-haloalkylsulfanyl having 1 to 9 identical or different halogen atoms; C1-C6-alkylsulfonyl; C1-C6-haloalkylsulfonyl having 1 to 9 identical or different halogen atoms; C2-C12-alkenyl; C2-C12-alkynyl; C3-C7-cycloalkyl; tri(C1-C8)alkylsilyl; each of which is optionally substituted; Y1and Y2independently of one another represent hydrogen, halogen, C1-C16-alkyl; C1-C6-haloalkyl having 1 to 9 identical or different halogen atoms; C1-C8-alkylsulfanyl; phenyl; each of which is optionally substituted; or Y1and Y2can form together with the carbon to which they are attached a C3-C8-cycloalkyl or a C3-C8-cycloalkenyl or a saturated 5, 6 or 7 membered heterocycle; each of which is optionally substituted; Rc represent C1-C16-alkyl; C1-C16-haloalkyl having 1 to 9 identical or different halogen atoms; C3-C8-cycloalkyl; (C3-C8-cycloalkyl)-C1-C8-alkyl; (C3-C8-cycloalkyl)-C3-C8-cycloalkyl; C2-C16-alkenyl-C1-C16-alkyl; C2-C16-alkynyl-C1-C16-alkyl; C1-C8-arylalkyl which is optionally substituted by up to 6 identical or different groups Rb; each of which is optionally substituted; provided that when, T represents oxygen, both Q and X2 represents hydrogen, and only one group selected from R1, R2, R3 and R4 represents hydrogen, then n represents 0. |