发明名称 Oxo-nitrogenated complex of lanthanides, catalytic system comprising said oxo-nitrogenated complex and process for the (co)polymerization of conjugated dienes
摘要 An oxo-nitrogenated complex of lanthanides having general formula (I) or (II). Said oxo-nitrogenated complex of lanthanides having general formula (I) or (II) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.;
申请公布号 US9200101(B2) 申请公布日期 2015.12.01
申请号 US201214344016 申请日期 2012.09.13
申请人 Versalis S.P.A. 发明人 Ricci Giovanni;Sommazzi Anna;Leone Giuseppe;Boglia Aldo;Masi Francesco
分类号 C08F136/06;C08F36/00;C08F136/00;C08F136/08;B01J31/00 主分类号 C08F136/06
代理机构 Tarolli, Sundheim, Covell & Tummino LLP 代理人 Tarolli, Sundheim, Covell & Tummino LLP
主权项 1. An oxo-nitrogenated complex of lanthanides having general formula (I) or (II): wherein: Ln is neodymium (Nd), lanthanum (La), praseodymium (Pr), gadolinium (Gd), europium (Eu), terbium (Tb), samarium (Sm), or erbium (Er); R1 and R2, equal to or different from each other, represent a hydrogen atom; or they are selected from linear or branched C1-C20 alkyl groups, cycloalkyl groups optionally substituted, or aryl groups optionally substituted; R3 represents a hydrogen atom; or it is selected from linear or branched C1-C20 alkyl groups, cycloalkyl groups optionally substituted, or aryl groups optionally substituted; or R3 represents a ketoimine group having the formula: wherein R′ and R″, equal to or different from each other, represent a hydrogen atom, or they are selected from linear or branched C1-C20 alkyl groups, cycloalkyl groups optionally substituted, or aryl groups optionally substituted; Y represents an oxygen atom; or a —N—R4 group wherein R4 represents a hydrogen atom, or it is selected from linear or branched C1-C20 alkyl groups, or cycloalkyl groups optionally substituted; or, when Y represents a —N—R4 group, R2 and R4 can be optionally bound to each other so to form, together with the other atoms to which they are bound, a saturated, unsaturated or aromatic cycle containing from 3 to 6 carbon atoms, optionally substituted with linear or branched C1-C20 alkyl groups, said cycle optionally containing other heteroatoms; and X1, X2 and X3, equal to or different from each other, represent a halogen atom; or they are selected from linear or branched C1-C20 alkyl groups, —OCOR5 or —OR5 groups wherein R5 is selected from linear or branched C1-C20 alkyl groups.
地址 San Donato Milanese IT