发明名称 |
METHOD FOR THE PRODUCTION OF POLY(2-OCTYL CYANOACRYLATE)-POLYISOBUTYLENE CO-NETWORK, AND SUPER INITIATORS THEREFOR |
摘要 |
A method for increasing the rate of polymerization of 2-octyl cyanoacrylate, or the rate of copolymerization of 2-octyl cyanoacrylate and a tri-telechelic star polymer comprising polyisobutylene terminated with cyanoacrylate groups ((PIB-CA)3) to form a co-network, is provided. The method comprise initiating the polymerization of 2-octyl cyanoacrylate, or the copolymerization of 2-octyl cyanoacrylate and a tri-telechelic star polymer comprising polyisobutylene terminated with cyanoacrylate groups ((PIB-CA)3) to form the co-network, with an initiator selected from the group consisting of cyclic tertiary aliphatic amines optionally dissolved in a non-aqueous solvent. The cyclic tertiary aliphatic amines are selected from the group consisting of azabicyclo[2.2.2]-octane (ABCO), and 1,4-diazabicyclo[2.2.2]-octane (DABCO). |
申请公布号 |
WO2015175014(A1) |
申请公布日期 |
2015.11.19 |
申请号 |
WO2014US61528 |
申请日期 |
2014.10.21 |
申请人 |
KENNEDY, JOSEPH;SZANKA, ISTVAN;SZANKA, AMALIA;THE UNIVERSITY OF AKRON |
发明人 |
KENNEDY, JOSEPH;SZANKA, ISTVAN;SZANKA, AMALIA |
分类号 |
C08F265/08 |
主分类号 |
C08F265/08 |
代理机构 |
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代理人 |
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地址 |
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