发明名称 LAUNDRY CARE COMPOSITIONS
摘要 A laundry care composition comprises a laundry care ingredient or adjunct and at least one compound that is capable of changing from a first color state (i.e., the initial color state in the composition) to a second color state that is perceptibly different from the first color state. A method for treating textile articles comprises the steps of: (a) providing a laundry care composition as described above; (b) adding the laundry care composition to a liquid medium; and (c) placing the textile articles in the liquid medium.
申请公布号 US2015322384(A1) 申请公布日期 2015.11.12
申请号 US201514704154 申请日期 2015.05.05
申请人 MILLIKEN & COMPANY 发明人 Butterfield Benjamin R.;Torres Eduardo;Dey Sanjeev K.;Hong Michael;Qin Haihu;Valenti Dominick J.
分类号 C11D3/42;C11D3/30 主分类号 C11D3/42
代理机构 代理人
主权项 1. A laundry care composition comprising a laundry care ingredient and at least one compound conforming to a structure selected from the group consisting of Formulae (I)-(XC) belowwherein X1 and X2 are selected from the group consisting of a carbon atom and a nitrogen atom; a is an integer from 0 to 5, provided a is an integer from 0 to 4 when one of X1 and X2 is a nitrogen atom and a is an integer from 0 to 3 when both X1 and X2 are nitrogen atoms; each R1 is independently selected from the group consisting of halogens, a hydroxy group, a nitro group, alkyl groups, substituted alkyl groups, —S(O)2OH, —S(O)2O−[M+], —C(O)OR5, —C(O)R5, —C(O)NR5R6, —NC(O)OR5, —NC(O)SR5, —OR5, —NR5R6, —S(O)2R5, —S(O)2NR5R6, and —P(O)2R5; M is a cation; R5 and R6 are independently selected from the group consisting of hydrogen, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, and Ra; R2 and R3 are independently selected from the group consisting of aryl groups, substituted aryl groups, heteroaryl groups, and substituted heteroaryl groups, provided at least one of R2 and R3 is heteroaryl group or a substituted heteroaryl group when both X1 and X2 are carbon atoms; L1 is selected from the group consisting of hydrogen, halogens, a hydroxy group, a cyano group, and —OR8; R8 is selected from the group consisting of alkyl groups and substituted alkyl groups;wherein X10 is selected from the group consisting of —C(O)— and —S(O)2; d is an integer from 0 to 4; each R10 is independently selected from the group consisting of halogens, a nitro group, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, —S(O)2OH, —S(O)2O−[M+], —C(O)OR5, —C(O)R5, —C(O)NR5R6, —NC(O)OR5, —NC(O)SR5, —OR5, —NR5R6, —S(O)2R5, —S(O)2NR5R6, and —P(O)2R5; provided at least one of R2 and R3 is selected from the group consisting of heteroaryl groups and substituted heteroaryl groups;wherein e and f are independently integers from 0 to 4; each R20 and R21 is independently selected from the group consisting of halogens, a nitro group, alkyl groups, substituted alkyl groups, —NC(O)OR5, —NC(O)SR5, —OR5, and —NR5R6; each R25 is independently selected from the group consisting of saccharide residues (i.e., monosaccharide residues, disaccharide residues, oligosaccharide residues, and polysaccharide residues), —C(O)R5, —C(O)OR5, —C(O)NR5R6; and each R22 and R23 is independently selected from the group consisting of hydrogen, alkyl groups, and substituted alkyl groups;wherein R30 is selected from the group consisting of —OR36 and —NR36R37, each R36 and R37 is independently selected from the group consisting of hydrogen, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, acyl groups, —C(O)OR5, —C(O)R5, and —C(O)NR5R6; g and h are independently integers from 0 to 4; each R31 and R32 is independently selected from the group consisting of alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, —S(O)2OH, —S(O)2O−[M+], —C(O)OR5, —C(O)R5, —C(O)NR5R6, —NC(O)OR5, —NC(O)SR5, —OR5, —NR5R6, —S(O)2R5, —S(O)2NR5R6, and —P(O)2R5; R34 and R35 are independently selected from the group consisting of hydrogen, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, and Ra; R33 is selected from the group consisting of hydrogen, —S(O)2R5, —C(O)N(H)R5; —C(O)OR5; and —C(O)R5; X30, X31, X32, and X33 are independently selected from the group consisting of a carbon atom and a nitrogen atom, provided no more than two of X30, X31, X32, and X33 are nitrogen atoms;wherein X40 is selected from the group consisting of an oxygen atom, a sulfur atom, and NR45; R45 is selected from the group consisting of alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, —S(O)2OH, —S(O)2O−[M+], —C(O)OR5, —C(O)R5, and —C(O)NR5R6; R40 and R41 are independently selected from the group consisting of —OR5 and —NR5R6; j and k are independently integers from 0 to 3; each R42 and R43 is independently selected from the group consisting of alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, —S(O)2R5, —C(O)NR5R6, —NC(O)OR5, —NC(O)SR5, —C(O)OR5, —C(O)R5, —OR5, —NR5R6; R44 is selected from the group consisting of —C(O)R5, —C(O)NR5R6, —C(O)OR5, and —C(O)OR5,wherein R50, R51, and R52 are independently selected from the group consisting of aryl groups, substituted aryl groups, heteroaryl groups, and substituted heteroaryl groups; Z is an anion; m and n are independently positive integers; y is the charge of the anion; the values of m, n, and y satisfy the following equation m=(−1)·y·n;wherein R54 and R55 are independently selected from the group consisting of aryl groups, substituted aryl groups, heteroaryl groups, and substituted heteroaryl groups; R53 is selected from the group consisting of arenediyl groups, substituted arenediyl groups, heteroarenediyl groups, and substituted heteroarenediyl groups; p is a positive integer; the values of p, n, and y satisfy the following equation 2m=(−1)·y·n;wherein X60 is selected from the group consisting of a nitrogen atom and a sulfur atom; X61 is selected from the group consisting of an oxygen atom and a sulfur atom; X62 is selected from the group consisting of a carbon atom and a nitrogen atom; q and r are independently integers from 0 to 4; each R60 and R61 is independently selected from the group consisting of halogens, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, —OR5, and —NR5R6; if q or r is 2 or greater, adjacent R60 and R61 groups can be combined to form an aryl group or a substituted aryl group; R62 is selected from the group consisting of alkyl groups and substituted alkyl groups;wherein X70 is selected from the group consisting of an oxygen atom, a nitrogen atom, and a sulfur atom; X71 is selected from the group consisting of a carbon atom and a nitrogen atom; s and t are independently integers from 0 to 4; each R70 and R71 are independently selected from the group consisting of halogens, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, —NC(O)OR5, —NC(O)SR5, —OR5, and —NR5R6; if s or t is 2 or greater, adjacent R70 and R71 groups can be combined to form an aryl group or a substituted aryl group;wherein R80 and R81 are independently selected from the group consisting of alkenyl groups, substituted alkenyl groups, aryl groups, substituted aryl groups, heteroaryl groups, and substituted heteroaryl groups; R82, R83, R84, and R85 are independently selected from the group consisting of hydrogen, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, —C(O)OR5, —C(O)R5, —C(O)NR5R6, —NC(O)OR5, —NC(O)SR5, —OR5, and —S(O)2R5; further, R82 and R85 can be combined to form a bridging alkanediyl group, a bridging oxygen atom, a bridging nitrogen atom, or a bridging sulfur atom;wherein u is an integer from 0 to 3; v and w are independently integers from 0 to 4; R90, R91, and R92 are independently selected from the group consisting of halogens, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, —OR5, —NR5R6, —C(O)OR5, —C(O)NR5R6, —NC(O)OR5, —NC(O)SR5, —S(O)2R5, and —S(O)2NR5R6;wherein Ra is selected from the group consisting of —Rx—O—Ry—Rz and —Ry—Rz; Rx is selected from the group consisting of alkanediyl groups and arenediyl groups; Rz is selected from the group consisting of hydrogen, alkyl groups, substituted alkyl groups, acyl groups, and Rb; Rb is a monovalent group conforming to a structure selected from the group consisting of Formulae (I)-(XC); and Ry is a divalent substituent selected from the group consisting of: (i) divalent substituents comprising two or more divalent repeating units independently selected from repeating units conforming to the structure of Formula (C)wherein R101 and R102 are independently selected from the group consisting of hydrogen, alkyl, hydroxyalkyl, aryl, alkoxyalkyl, and aryloxyalkyl; (ii) divalent substituents conforming to the structure of Formula (CX)wherein R111 and R112 are independently selected from the group consisting of hydrogen, hydroxyl, and C1-C10 alkyl, aa is an integer from 1 to 12, and bb is an integer greater than or equal to 1 (e.g., from 1 to 100); (iii) divalent substituents conforming to the structure of Formula (CXX)wherein R121 and R122 are independently selected from the group consisting of hydrogen, hydroxyl, and C1-C10 alkyl, cc is an integer from 1 to 12, and dd is an integer greater than or equal to 1 (e.g., from 1 to 100); (iv) divalent substituents conforming to the structure of Formula (CXXX)wherein R131, R132, and R133 are independently selected from alkyl and hydroxyalkyl, and ee is an integer greater than or equal to 1 (e.g., from 1 to 100); (v) divalent substituents conforming to the structure of Formula (CXL)wherein each R141 is independently selected from the group consisting of hydrogen and alkylamine groups, and ff is an integer greater than or equal to 1 (e.g., from 1 to 100); (vi) divalent substituents conforming to the structure of Formula (CL)wherein gg is an integer greater than or equal to 1 (e.g., from 1 to 100); (vii) divalent substituents conforming to the structure of Formula (CLX)wherein each R161 is independently selected from the group consisting of hydrogen and methyl, and hh is an integer greater than or equal to 1 (e.g., from 1 to 100); (viii) divalent substituents conforming to the structure of Formula (CLXX)wherein each R171, R172, and R173 is independently selected from the group consisting of hydrogen and —CH2CO2H, and jj is an integer greater than or equal to 1 (e.g., from 1 to 100); and (ix) divalent substituents comprising two or more substituents selected from the group consisting of substituents conforming to a structure of Formula (C), (CX), (CXX), (CXXX), (CXL), (CL), (CLX), or (CLXX).
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