发明名称 |
Metal oxide ultrafine fiber-based composite separator with heat resistance and secondary battery using same |
摘要 |
An ultrafine fiber-based composite separator comprising a fibrous porous body which comprises ultrafine metal oxide/polymer composite fibers, or ultrafine metal oxide fibers and a polymer resin coating layer formed on the surface thereof, the ultrafine fibers being continuously randomly arranged and layered, and obtained by electrospinning a metal oxide precursor sol-gel solution or a mixture of a metal oxide precursor sol-gel solution and a polymer resin solution, wherein the surface of the metal oxide/polymer composite fibers has a uniform mixing composition of the metal oxide and the polymer resin, in which the separator has a heat shrinkage rate at 150˜250° C. of 10% or less and does not break down due to melting at a temperature of 200° C. or lower, has low heat shrinkage rate, and superior heat resistance and ionic conductivity, being capable of providing improved cycle and power properties when used in manufacturing a battery. |
申请公布号 |
US9180412(B2) |
申请公布日期 |
2015.11.10 |
申请号 |
US201113088851 |
申请日期 |
2011.04.18 |
申请人 |
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发明人 |
Jo Seong Mu;Kim Dong Young;Jang Sung-Yeon |
分类号 |
H01M2/16;B01D67/00;C04B35/622;C04B35/624;C04B35/628;C04B35/634;D01D5/00;D01F1/10;D01F6/12;D01F9/08;H01M2/14;H01M10/052 |
主分类号 |
H01M2/16 |
代理机构 |
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代理人 |
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主权项 |
1. An ultrafine fiber-based composite separator comprising a fibrous porous body which comprises ultrafine metal oxide/polymer composite fibers, or ultrafine metal oxide fibers and a polymer resin coating layer formed on the surface thereof, the ultrafine fibers being continuously randomly arranged and layered, and obtained by electrospinning a homogenous mixture of a metal oxide precursor sol-gel solution and a polymer resin solution, wherein the surface of the metal oxide/polymer composite fibers has a uniform mixing composition of the metal oxide and the polymer resin, in which the separator has a heat shrinkage rate at 150˜250° C. of 10% or less and does not break down due to melting at a temperature of 200° C. or lower, and wherein the polymer resin solution comprises a polymer resin that swells in an electrolyte solution and/or a polymer resin that has a melting point of 180° C. or higher or is amorphous, or is a mixture thereof. |
地址 |
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