发明名称 |
PROCESS FOR SEPARATING VINYL ESTERS FROM A GAS STREAM COMPRISING ETHYLENE AND VINYL ESTERS |
摘要 |
Process for separating esters of vinyl alcohol from a gas stream comprising from 70 to 99.5% by weight of ethylene and from 0.5 to 30% by weight of esters of vinyl alcohol being at a pressure in the range of from 0.5 MPa to 10 MPa and a temperature in the range of from 5°C to 50°C comprising the steps of
a) cooling the gas stream in a first heat exchanger by means of a cooling medium to a temperature of from -5°C to 40°C;
b) withdrawing the not condensed part of the gas stream from the first heat exchanger and transferring it to a second heat exchanger;
c) cooling the gas stream in the second heat exchanger to a temperature of from -20°C to 5°C;
d) withdrawing the not condensed part of the gas stream from the second heat exchanger, reducing the pressure of the gas stream to from 0.5 MPa to 3 MPa and transferring it to a separation vessel;
e) withdrawing the not condensed part of the gas stream from the separation vessel and transferring it as cooling medium to the second heat exchanger; and
f) withdrawing the cooling medium as ethylene gas stream with a reduced content of esters of vinyl alcohol from the second heat exchanger,
and process for copolymerizing ethylene and esters of vinyl alcohol in the presence of free-radical polymerization initiators at pressures in the range of from 110 MPa to 500 MPa and temperatures in the range of from 100°C to 350°C in a continuously operated polymerization apparatus comprising such a process for separating esters of vinyl alcohol from a gas stream comprising from 70 to 99.5% by weight of ethylene and from 0.5 to 30% by weight of esters of vinyl alcohol. |
申请公布号 |
EP2935366(A1) |
申请公布日期 |
2015.10.28 |
申请号 |
EP20130818709 |
申请日期 |
2013.12.16 |
申请人 |
BASELL POLYOLEFINE GMBH |
发明人 |
NEUMANN, ERICH;WOLF, CHRISTOPH;LITTMANN, DIETER |
分类号 |
C08F210/02;C07C67/54;C08F2/00 |
主分类号 |
C08F210/02 |
代理机构 |
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代理人 |
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地址 |
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