发明名称 Process for producing ethylene by chlorination of ethane and dehydrochlorination of ethyl chloride
摘要 Ethylene is produced from ethane in three steps: first, ethane is oxychlorinated to produce ethyl chloride and water; second, ethyl chloride from the first step is cracked to produce ethylene and hydrogen chloride; and third, the hydrogen chloride from the second step is recycled to the front step.
申请公布号 US9169168(B2) 申请公布日期 2015.10.27
申请号 US201313859886 申请日期 2013.04.10
申请人 发明人 Stauffer John E.
分类号 C07C1/30;C07C2/86;C07C17/154;C01B7/03 主分类号 C07C1/30
代理机构 Young Basile Hanlon & MacFarlane 代理人 Young Basile Hanlon & MacFarlane
主权项 1. A process for the manufacture of ethylene from ethane comprising the steps of: a) oxychlorinating ethane with hydrogen chloride and oxygen to give ethyl chloride and water at a temperature in the range of 350° to 400° C. in the presence of a catalyst; b) vapor phase cracking the ethyl chloride to give ethylene and hydrogen chloride at a temperature in the range of 325° to 375° C. over a catalyst consisting of silica alumina; and c) recycling hydrogen chloride produced in step b for use in step a.
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