Thermo-latent catalysts, production and use of same

摘要

Use of one or more metal compounds (Q), is claimed. Use of one or more metal compounds of formulae (X aY1 ( m - a )L dMA) (A), ((X bY1 ( m - b - 1 )L eMB) 2O) (B) and ((MC(X cY1 ( m - c - 2 )L f)O) n) (C), is claimed. MA, MB : Sn, Ti, Zr, Hf, Fe, or Zn; MC : Sn, Ti, Zr, Hf, or Fe; either X : -SR1; and Y1 : halo, OR2, OC(O)R2, OS(O) 2R2, NR2R3, NR2C(O)R3, NR2S(O) 2R3, OP(O)(OR2) (OR3), OP(O)(OR2)R3 or OP(O)R2R3; or XY1+M atom : ring; L : neutral ligand; m : 2 (if M is Zn), 3 (if M is Fe) or 4 (if M is Sn, Ti, Zr, or Hf); R1 : 1-18C alkyl, 2-18C alkenyl, 2-18C alkynyl (all linear or branched), 3-10C cycloalkyl, 6-10C aryl or C(O)(1-18C-alkyl), where R1 is optionally substituted by OH, O(1-18C-alkyl), O(2-18C-alkenyl), O(2-18C-alkynyl), O(6-10C-aryl), OC(O)(1-18C-alkyl), OC(O)(2-18C-alkenyl), OC(O)(2-18C-alkynyl), C(O)(6-10C-aryl), OS(O) 2(1-18C-alkyl), OS(O) 2(2-18C-alkenyl), OS(O) 2(2-18C-alkynyl), OS(O) 2(6-10C-aryl), C(O)H, C(O)(1-18C-alkyl), C(O)(2-18C-alkenyl), C(O)(2-18C-alkynyl), C(O)(6-10C-aryl), C(O)OH, C(O)O(1-18C-alkyl), C(O)O(2-18C-alkenyl), C(O)O(2-18C-alkynyl), C(O)O(6-10C-aryl), SH, S(1-18C-alkyl), S(2-18C-alkenyl), S(2-18C-alkynyl), S(6-10C-aryl), S(O) 2(1-18C-alkyl), S(O) 2(2-18C-alkenyl), S(O)(2-18C-alkynyl), S(O) 2(6-10C-aryl), S(O) 2OH, S(O) 2O(1-18C-alkyl), S(O) 2O(2-18C-alkenyl), S(O) 2O(2-18C-alkynyl), S(O) 2O(6-10C-aryl), 1-18C-alkyl, 2-18C-alkenyl, 2-18C-alkynyl, 3-10C-cycloalkyl, 6-10C-aryl, halo, CF 3 or CN; R2, R3 : linear or branched 1-18C-alkyl, linear or branched 2-18C-alkenyl, linear or branched 2-18C-alkynyl, 3-10C-cycloalkyl or 6-10C-aryl (all optionally substituted by OH, O(1-18C-alkyl), O(6-10C-aryl), OC(O)(1-18C-alkyl), OC(O)(6-10C-aryl), OS(O) 2(1-18C-alkyl), OS(O) 2(6-10C-aryl), C(O)H, C(O)(1-18C-alkyl), C(O)(6-10C-aryl ), C(O) OH, C(O)O(1-18C-alkyl ), C(O)O(6-10C-aryl), SH, S(1-18C-alkyl), S(6-10C-aryl), S(O) 2(1-18C-alkyl), S(O) 2(6-10C-aryl), S(O) 2OH, S(O) 2O(1-18C-alkyl), S(O) 2O(6-10C-aryl), 1-18C-alkyl, 3-10C-cycloalkyl, 6-10C-aryl, halo, CF 3 or CN), or H; a : 1-m; b : 1 to m-1; c : 1 to m-2; d-f : 0 to 6-m; and n : 3-12.