Fuel cell separator sealing material and fuel cell separator

摘要

For use in a fuel cell separator comprising a separator substrate, a primer layer, and an elastomeric seal, a sealing material comprises a primer composition containing Si—H groups of which the primer layer is formed, and a liquid addition-curable silicone rubber composition containing alkenyl groups and Si—H groups of which the elastomeric seal is formed. A molar ratio of the total amount of Si—H groups to the total amount of alkenyl groups per unit weight of the primer composition and the silicone rubber composition is in the range: 5.0

主权项

1. A sealing material for use in a fuel cell separator comprising:
a separator substrate, a primer layer thereon, and an elastomeric sealing material on the primer layer, said sealing material comprising:
a primer composition containing Si—H functional groups of which the primer layer is formed, anda liquid addition-curable silicone rubber composition containing alkenyl groups and Si—H functional groups of which the elastomeric sealing material is formed,wherein a molar ratio of a total amount of the Si—H functional groups to a total amount of the alkenyl groups per unit weight of the primer composition and the liquid addition-curable silicone rubber composition is in the range: 5.0<(total amount of the Si—H functional groups)/(total amount of the alkenyl groups)<50.0,wherein said liquid addition-curable silicone rubber composition comprises:(A) 100 parts by weight of a liquid organopolysiloxane containing at least two of the alkenyl groups each attached to a silicon atom in a molecule,(B) 0.5 to 20 parts by weight of an organohydrogenpolysiloxane containing at least three of the Si—H functional groups in a molecule,(C) 5 to 30 parts by weight of fumed silica having a specific surface area of 50 to 400 m2/g, and(D) an addition reaction catalyst from a platinum group metal,a molar ratio of the Si—H functional groups in component (B) to the alkenyl groups in component (A) being in the range: 0.8≦the Si—H functional groups/the alkenyl groups≦3.0.