发明名称 Method for producing alcohol
摘要 Disclosed is a method for producing an alcohol using a device for reducing carbon dioxide by light energy. In this device, a cathode electrode includes copper or a copper compound, and an anode electrode includes a region including a nitride semiconductor layer in which an AlxGa1-xN layer (0<x≦1) and a GaN layer are laminated. A first electrolytic solution consisting of an aqueous potassium chloride solution (aqueous KCl solution) is contained in a cathode chamber in which the cathode electrode is placed. A second electrolytic solution including an aqueous sodium hydroxide solution (aqueous NaOH solution) is contained in an anode chamber in which the anode electrode is placed.
申请公布号 US9157158(B2) 申请公布日期 2015.10.13
申请号 US201414450999 申请日期 2014.08.04
申请人 PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD. 发明人 Deguchi Masahiro;Hashiba Hiroshi;Yotsuhashi Satoshi;Yamada Yuka
分类号 C25B3/04;C25B9/08;C25B1/02;C07C29/15;C25B1/00;C25B9/16;B01J35/00 主分类号 C25B3/04
代理机构 McDermott Will & Emery LLP 代理人 McDermott Will & Emery LLP
主权项 1. A method for producing an alcohol using a device for reducing carbon dioxide by light energy, the method comprising the steps of: (a) preparing the device for reducing carbon dioxide, the device including a cathode chamber, an anode chamber, and a proton conducting membrane, wherein the cathode chamber contains a cathode electrode,the cathode electrode includes copper or a copper compound,the anode chamber contains an anode electrode,the anode electrode includes a region including a nitride semiconductor layer in which an AlxGa1-xN layer (0<x≦1) and a GaN layer are laminated,a first electrolytic solution consisting of an aqueous potassium chloride solution (aqueous KCl solution) is contained in the cathode chamber,a second electrolytic solution including an aqueous sodium hydroxide solution (aqueous NaOH solution) is contained in the anode chamber,the cathode electrode is in contact with the first electrolytic solution,the anode electrode is in contact with the second electrolytic solution,the proton conducting membrane is interposed between the cathode chamber and the anode chamber,the first electrolytic solution contains carbon dioxide,the cathode electrode is electrically connected to the anode electrode, anda power source that is electrically connected to the cathode electrode and the anode electrode is not provided between the cathode electrode and the anode electrode; and (b) irradiating the anode electrode with light having a wavelength of 360 nm or less so as to reduce, at the cathode electrode, the carbon dioxide contained in the first electrolytic solution and to produce the alcohol.
地址 Osaka JP