Process for producing (meth)acrylic acids

摘要

A process for producing (meth)acrylic acid or (meth)acrylic esters, which comprises a reaction step comprising vapor phase catalytic oxidation of propylene, propane or isobutylene and, if necessary, a reaction step comprising an esterification step, characterized in that at the time when a high boiling mixture (hereinafter referred to as a high boiling material) containing a Michael addition product, is decomposed in a decomposition reactor to recover (meth)acrylic acids, while forcibly imparting a liquid flow in the circumferential direction to a liquid reaction residue in the decomposition reactor, the liquid reaction residue is discharged. In a process for recovering a valuable substance by thermally decomposing the high boiling material containing the Michael addition product of (meth)acrylic acids, it is possible to transfer the decomposition residue from the decomposition reactor to the storage tank without clogging, whereby a long-term continuous operation is possible.