主权项 |
1. An ethylene-based polymer formed from ethylene and at least one monomeric chain transfer agent (monomeric CTA) comprising a copolymerization end and a chain transfer end;
wherein the polymer comprises a majority amount of polymerized ethylene, based on the weight of the polymer; and wherein the chain transfer end of the monomeric chain transfer agent is selected from the group consisting of the following 1) through 4):where R1 is selected from H, C1-C22 alkyl, C3-C8 cycloalkyl, CN, Phenyl, COCH3, Cl, Br, or I;where R2, R3 are each independently selected from H, C1-C22 alkyl, C3-C8 cycloalkyl, CN, Phenyl, or COCH3;where n is from 1 to 6;where R4 is selected from H, C1-C22 alkyl, C3-C8 cycloalkyl, Phenyl, Cl, Br, or I;
and wherein the ethylene-based polymer comprises ethylene and said at least one monomeric CTA as the only monomeric units. |