发明名称 PYRONE COMPOUNDS AND HERBICIDES COMPRISING THE SAME
摘要 The present invention provides a compound having an excellent efficacy for controlling weeds. A pyrone compound of formula (I):;;wherein m is 1, 2 or 3; n is an integer of any one of 1 to 5; X represents O, S, S(O) or S(O)2; R1 represents a hydrogen atom or a methyl group; R2 and R3 represents a hydrogen atom, an C1-6 alkyl group and the like; R4 represents an C6-10 aryl group or a five- to six-membered heteroaryl group; G represents a hydrogen atom and the like; Z represents a halogen atom, a cyano group, a nitro group, a phenyl group, an C1-6 alkyl group and the like; is useful as an active ingredient for herbicides.
申请公布号 US2015274691(A1) 申请公布日期 2015.10.01
申请号 US201314433722 申请日期 2013.10.07
申请人 SUMITOMO CHEMICAL COMPANY LIMITED 发明人 Nakashima Yosuke;Jin Yoshinobu
分类号 C07D309/38;C07D405/12;A01N43/40;A01N43/82;C07D417/12;A01N43/78;C07D407/12;A01N43/16;C07D409/12 主分类号 C07D309/38
代理机构 代理人
主权项 1. A pyrone compound of formula (1):wherein m is 1, 2 or 3; n is an integer of any one of 1 to 5; X represents O, S, S(O) or S(O)2; R1 represents a hydrogen atom or a methyl group; R2 and R3 represent independently of each other a hydrogen atom, a halogen atom, an C1-6 alkyl group, a C1-6 haloalkyl group, a C3-8 cycloalkyl group or a C3-8 halocycloalkyl group, alternatively R2 and R3 connect each other to represent an C2-5 alkylene chain, or R2 and R3 combine each other to represent an C1-3 alkylidene group optionally having one or more halogen atoms (with the proviso that when m is 2 or 3, two or three R2 may be same or different to each other and two or three R3 may be same or different to each other); R4 represents an C6-10 aryl group or a five- to six-membered heteroaryl group (with the proviso that the C6-10 aryl group and the five- or six-membered heteroaryl group may have optionally one or more substituents selected from the group consisting of a halogen atom, a cyano group, a nitro group, an amino group, an (C1-6 alkyl)amino group, an (C1-6 alkyl)(C1-6 alkyl)amino group, a pentafluorothio group, an C1-6 alkyl group, an C2-6 alkenyl group, an C2-6 alkynyl group, an C1-6 alkoxy group, an C1-6 alkylthio group, an C3-6 alkenyloxy group, an C3-6 alkynyloxy group, an C6-10 aryl group, an C6-10 aryloxy group, an C1-6 alkylsulfinyl group, an C1-6 alkylsulfonyl group, a hydroxyl group, an (C1-6 alkyl)carbonyl group, a hydroxycarbonyl group, a (C1-6 alkoxy)carbonyl group and an (C6-10 aryl)C1-6 alkoxy group, and when two or more substituents exist, the substituents may be same or different to each other; and the C1-6 alkyl group, the C2-6 alkenyl group, the C2-6 alkynyl group, the C1-6 alkoxy group, the C1-6 alkylthio group, the C3-6 alkenyloxy group, the C3-6 alkynyloxy group, the C6-10 aryl group, the C6-10 aryloxy group, the C1-6 alkylsulfinyl group, the C1-6 alkylsulfonyl group, the (C1-6 alkyl)carbonyl group, the (C1-6 alkoxy)carbonyl group and the (C6-10 aryl)C1-6 alkoxy group may each have one or more halogen atoms or C1-3 haloalkyl groups, and when two or more halogen atoms or C1-3 haloalkyl groups exist, the halogen atoms or the C1-3 haloalkyl groups may be same or different to each other respectively); G represents a hydrogen atom or a group of any one of the following formulae:{wherein L represents an oxygen atom or a sulfur atom; R5 represents an C1-6 alkyl group, a C3-8 cycloalkyl group, an C2-6 alkenyl group, an C2-6 alkynyl group, an C6-10 aryl group, an (C6-10 aryl)C1-6 alkyl group, an C1-6 alkoxy group, a C3-8 cycloalkoxy group, an C3-6 alkenyloxy group, an C3-6 alkynyloxy group, an C6-10 aryloxy group, an (C6-10 aryl)C1-6 alkoxy group, an (C1-6 alkyl)(C1-6 alkyl)amino group, an (C3-6 alkenyl)(C3-6 alkenyl)amino group, an (C1-6 alkyl)(C6-10 aryl)amino group or a five- to six-membered heteroaryl group (with the proviso that these groups may each have one or more halogen atoms, and when two or more halogen atoms exist, the halogen atoms may be same or different to each other; and the C3-8 cycloalkyl group, the C6-10 aryl group, an aryl moiety of the (C6-10 aryl)C1-6 alkyl group, the C3-8 cycloalkoxy group, the C6-10 aryloxy group, an aryl moiety of the (C6-10 aryl)C1-6 alkoxy group, an aryl moiety of the (C1-6 alkyl)(C6-10 aryl)amino group and a five- to six-membered heteroaryl group may each have one or more C1-6 alkyl groups, and when two or more C1-6 alkyl groups exist, the alkyl groups may be same or different to each other); R6 represents an C1-6 alkyl group, an C6-10 aryl group or an (C1-6 alkyl)(C1-6 alkyl)amino group (with the proviso that these groups may each have one or more halogen atoms and when two or more halogen atoms exist, the halogen atoms may be same or different to each other; andthe C6-10 aryl group may have optionally one or more C1-6 alkyl groups and when two or more C1-6 alkyl groups exist, the alkyl groups may be same or different to each other); R7 represents a hydrogen atom or an C1-6 alkyl group; W represents an C1-6 alkoxy group, an C1-6 alkylthio group, an C1-6 alkylsulfinyl group or an C1-6 alkylsulfonyl group (with the proviso that these groups may each have one or more halogen atoms and when two or more halogen atoms exist, the halogen atoms may be same or different to each other)}; Z represents a halogen atom, a cyano group, a nitro group, an C1-6 alkyl group, an C2-6 alkenyl group, an C2-6 alkynyl group, an C1-6 alkoxy group, an (C1-6 alkyl)carbonyl group, an C1-6 alkylthio group, an C6-10 aryloxy group, a five- or six-membered heteroaryloxy group, a C3-8 cycloalkyl group, an C6-10 aryl group or a five- to six-membered heteroaryl group (with the proviso that the C1-6 alkyl group, the C2-6 alkenyl group, the C2-6 alkynyl group, the C1-6 alkoxy group, the (C1-6 alkyl)carbonyl group and the C1-6 alkylthio group may each have one or more halogen atoms, and when two or more halogen atoms exist, the halogen atoms may be same or different to each other; and the C6-10 aryl group, the five- to six-membered heteroaryl group, the C6-10 aryloxy group and the five- to six-membered heteroaryloxy group may each have one or more substituents selected from the group consisting of a halogen atom, an C1-6 alkyl group and a C1-6 haloalkyl group, and when two or more substituents exist, the substituents may be same or different to each other; and the C3-8 cycloalkyl group may have optionally one or more substituents selected from the group consisting of a halogen atom and an C1-6 alkyl group, and when two or more substituents exist, the substituents may be same or different to each other;when n is an integer of 2 or more, Z may be same or different to each other).
地址 Tokyo JP