发明名称 METHOD FOR PRODUCING ESTER CONDENSED PRODUCT
摘要 A method for producing an ester condensed product, wherein an esterification reaction is effected by using a catalyst comprising a zirconium (IV) compound and/or a hafnium (IV) compound and an iron compound and/or a gallium compound; and a catalyst for use in the method. It is preferred that the zirconium (IV) compound is a compound represented by Zr(OH)a(OR1)b[wherein R 1 represents an acyl group or alkyl group, and each of a and b is 0 or an integer of 1 to 4 and the relationship of a + b = 4 is satisfied] or a zirconium (IV) halide. The method allows the production of an ester condensed product having a specific structure by the reaction of equimolar amounts of a carboxylic acid and an alcohol, with the inhibition of the formation of by-products, in good yield, on a large scale, and the catalyst exhibits good catalytic efficiency and is used in a small amount, is reusable and can be repeatedly used. The method can thus provide an industrial process which is desirable from the view point of green chemistry.
申请公布号 KR20060065726(A) 申请公布日期 2006.06.14
申请号 KR20067006493 申请日期 2006.04.03
申请人 JAPAN SCIENCE AND TECHNOLOGY AGENCY 发明人 ISHIHARA KAZUAKI;YAMAMOTO HISASHI
分类号 C07C67/08;C07C67/00;C07C69/767;C07D307/24 主分类号 C07C67/08
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