发明名称 |
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摘要 |
A continuous homogeneous cyanoethylation process, in which acrylonitrile is reacted with a compound containing a labile hydrogen atom to form a beta - substituted propionitrile derivative and in which the reaction zone is maintained at a cyanoethylation temperature, is characterised in that a relatively large amount of reactor effluent, i.e. 50-90 wt. %, is recycled to the reactor. High yields of cyanoethylated products are obtained. The process, e.g., has a yield in excess of 95 wt. % of 3,3'-ethylenedioxybis (propionitrile) from the reaction of ethylene glycol and acrylonitrile with the use of a catalyst, e.g., an aqueous alkali metal hydroxide. The products are useful intermediates for the manufacture of plastics and fibres. <IMAGE> |
申请公布号 |
DE2924133(C2) |
申请公布日期 |
1989.08.24 |
申请号 |
DE19792924133 |
申请日期 |
1979.06.15 |
申请人 |
SUNTECH INC., PHILADELPHIA, PA., US |
发明人 |
BUTTE JUN., WALTER ALBERT, WEST CHESTER, PA., US;CHERRY, WESLEY ROBERT, PROSPECT PARK, PA., US |
分类号 |
C07C255/13;C07B;C07C67/00;C07C253/00 |
主分类号 |
C07C255/13 |
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