| 摘要 |
A method for electrospinning nanofibers having a core-sheath, tubular, or composite structure is disclosed. The process uses a spinneret having first and second capillaries that channel first and second fluids in the spinneret, the second capillary surrounding the first. A high voltage is applied between the spinneret and a spaced conductive collector. In one embodiment, the first fluid is a mineral oil and the second fluid is a polymeric solution that may include a polymer, a catalyst, a solvent, and a sol-gel precursor. The as-spun nanofiber includes an oil core and a composite sheath. The oil may be removed to produce a composite tubular fiber or the polymer and oil may be removed by calcination to produce a ceramic tubular fiber. In other embodiments, miscible fluids are used to produce porous nanofibers, selected additives functionalize the surfaces of the nanofibers and/or conjugated polymers are used.
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