发明名称
摘要 The present invention relates to a method for preparing caprolactone, comprising converting 5-hydroxymethyl-2-furfuraldehyde by hydrogenation into at least one intermediate compound selected from the group of 2,5-tetrahydrofuran dimethanol, 1,6-hexanediol and 1,2,6-hexanetriol,and preparing caprolactone from said intermediate compound. Further, the invention relates to a method for preparing 1,2,6 hexanetriol comprising preparing 5-hydroxymethyl-2-furfaldehyde from a renewable source, converting 5-hydroxymethyl-2-furfaldehyde into 2,5-tetrahydrofuran dimethanol and converting 2,5-tetrahydrofuran dimethanol into 1,2,6 hexanetriol. Further, the invention relates to a method for preparing 1,6 hexanediol from 1,2,6-hexanetriol, wherein 1,2,6-hexanetriol is subjected to a ring closure reaction, thereby forming 2-hydropyranyl-methanol, and the 2-hydropyranyl-methanol is hydrogenated, thereby forming 1,6 hexane diol.
申请公布号 JP2013531638(A) 申请公布日期 2013.08.08
申请号 JP20130512556 申请日期 2011.03.23
申请人 发明人
分类号 C07D313/04;C07B61/00;C07C29/132;C07C31/20;C07C31/22;C07D223/10;C07D307/50 主分类号 C07D313/04
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