发明名称 |
CONVERSION OF ETHANOL TO A REACTION PRODUCT COMPRISING 1-BUTANOL USING HYDROXYAPATITE CATALYSTS |
摘要 |
Catalytic processes to produce a reaction product comprising 1-butanol by contacting a reactant comprising ethanol with a catalyst composition under suitable reaction conditions are provided. The catalyst composition may comprise a hydroxyapatite of the Formula (MwM'xM''yM'''z)5(PO4)3(OH), wherein M is Mg; M' is Ca; M'' is Sr; M''' is Ba; w is any number between 0 and 1 inclusive; x is any number from 0 to less than 0.5; y is any number between 0 and 1 inclusive; z is any number between 0 and 1 inclusive; and w+x+y+z=1. Base-treated catalyst compositions may be used. Also provided are processes for contacting an initial catalyst composition comprising the hydroxyapatite with a base to produce a base-treated catalyst composition, and the base-treated catalyst compositions so obtained. |
申请公布号 |
US2013303362(A1) |
申请公布日期 |
2013.11.14 |
申请号 |
US201313942759 |
申请日期 |
2013.07.16 |
申请人 |
E I DU PONT DE NEMOURS AND COMPANY |
发明人 |
FAGAN PAUL JOSEPH;CALVARESE THOMAS G.;DAVIS RONALD JAMES;OZER RONNIE |
分类号 |
B01J27/182;B01J27/18;C07C29/34 |
主分类号 |
B01J27/182 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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