发明名称 BIOMASS DERIVED METHYL METHACRYLATE AND CORRESPONDING MANUFACURING METHOD, USES AND POLYMERS
摘要 The invention relates to methyl methacrylate characterized in that at least one portion of the carbons thereof is biologically sourced and, more specifically, in that it contains between 0.2×10−10 and 1.2×10−10 wt.-% of 14C in relation to total carbon weight according to the ASTM D6866 standard. The preparation method comprises the use of acetone cyanohydrin as a raw material, said acetone cyanohydrin being obtained by condensing cyanohydric acid on acetone, and the methyl methacrylate is prepared using a process involving the addition of methanol. According to the invention, at least one from among the acetone, cyanohydric acid and methanol is obtained by means of a reaction or series of reactions involving the biomass.
申请公布号 US2014154758(A1) 申请公布日期 2014.06.05
申请号 US201414175291 申请日期 2014.02.07
申请人 Croizy Camille;CROIZY PAULINE;Campora Lucie;ARKEMA FRANCE 发明人 DUBOIS JEAN-LUC;Croizy Jean Francois
分类号 C07C67/22 主分类号 C07C67/22
代理机构 代理人
主权项 1. A method for the manufacture methyl methacrylate, comprising: a) condensing hydrocyanic acid with acetone to form acetone cyanohydrin, and b) introducing methanol to form methyl methacrylate,wherein at least one from acetone, hydrocyanic acid and methanol was obtained by a reaction or a succession of reactions starting from biomass, and wherein the methyl methacrylate comprises at least 0.2×10−10% by mass of 14C relative to the total mass of carbon according to standard ASTM D6866.
地址 Villeneuve D'Ascq FR