发明名称 Cyclopropyl Substituted Metallocene Catalysts
摘要 This invention relates to a novel group 2, 3 or 4 transition metal metallocene catalyst compound having at least one arenyl ligand substituted with: 1) a cyclopropyl group and, optionally, 2) at least one other group, such as a hydrocarbyl, a heteroatom or a heteroatom containing group.
申请公布号 US2015025207(A1) 申请公布日期 2015.01.22
申请号 US201414324427 申请日期 2014.07.07
申请人 ExxonMobil Chemical Patents Inc. 发明人 Canich Jo Ann M.;Voskoboynikov Alexander Z.;Uborsky Dmitry V.;Borisov Ilya S.;Tsarev Alexey A.;Kulyabin Pavel S.;Sharikov Mikhail I.;Samsonov Oleg V.;Goryunov Georgy P.
分类号 C08F110/06;C08F110/02 主分类号 C08F110/06
代理机构 代理人
主权项 1. A metallocene compound represented by the formula (1): AeMXn-e wherein: e is 1 or 2; each A is a substituted monocyclic or polycyclic ligand that is pi-bonded to M and optionally includes one or more ring heteroatoms selected from boron, a group 14 atom that is not carbon, a group 15 atom, or a group 16 atom, and when e is 2 each A may be the same or different; provided that at least one A is substituted with at least one cyclopropyl substituent directly bonded to any sp2 carbon atom at a bondable ring position of the ligand, wherein the cyclopropyl substituent is represented by the formula: where each R′ is, independently, hydrogen, a substituted or unsubstituted hydrocarbyl group, or a halogen; e is 1 or 2; M is a transition metal atom having a coordination number of n and selected from group 3, 4, or 5 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom; n is 3, 4, or 5; and each X is a univalent anionic ligand, or two Xs are joined and bound to the metal atom to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand.
地址 Baytown TX US
您可能感兴趣的专利