| 摘要 |
<p>A photoelectric conversion element including an electrically conductive support, a photoconductor layer containing an electrolyte, a charge transfer layer containing an electrolyte, and a counter electrode, wherein the photoconductor layer contains semiconductor fine particles carrying a metal complex dye represented by Formula (I); a metal complex dye, a dye solution, a dye-adsorbed electrode, a dye-sensitized solar cell, and a method for producing dye-sensitized solar cell:
€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒM(LA)(LD)(LX) mX €¢(CI) mY €ƒ€ƒ€ƒ€ƒ€ƒFormula (I)
M represents a metal ion, LA represents a tridentate ligand represented by Formula (AL), LD represents a bidentate ligand or tridentate ligand, at least one of coordinating atoms therein being an anion; LX represents a monodentate ligand; CI represents a counter ion; mX is 0 or 1; mY is an integer of 0 to 3;
Rings A to C represent a nitrogen-containing aromatic heterocyclic ring; Z 1 and Z 2 represent a carbon atom or a nitrogen atom; Anc1 to Anc3 represent an acidic group; X 1 and X 3 represent a single bond or a linking group, X 2 is a single bond or a linking group that links through conjugation, and when X 2 is the linking group, X 2 contains an ethenylene group, an ethynylene group, an arylene group or a heteroarylene group, in the linking chain thereof; R 1 to R 3 represent a substituent; l1 and l3 are an integer of 1 to 4, l2 is an integer of 1 to 5, m1 and m3 is an integer of 0 to 4, m2 is an integer of 1 to 3, n1 and n2 are an integer of 0 to 3, and n3 is an integer of 0 to 4; when X 2 is the single bond, m1 or m3 is an integer of 1 to 4, and X 1 or X 3 represents the linking group.</p> |
