发明名称 |
Mixed metal oxide and sodium secondary battery |
摘要 |
A sodium secondary battery capable of reducing the amount used of a scarce metal element such as lithium and cobalt and moreover, ensuring a larger discharge capacity after repeating charge/discharge as compared with conventional techniques, and a mixed metal oxide usable as the positive electrode active material therefor. The mixed metal oxide comprises Na, Mn and M1 wherein M1 is Fe or Ni, with a Na:Mn:M1 molar ratio being a:(1−b):b wherein a is a value falling within the range of more than 0.5 and less than 1, and b is a value falling within the range of from 0.001 to 0.5. Another mixed metal oxide is a mixed metal oxide represented by the following formula (1): NaaMn1−bM1bO2 (1) wherein M1, a and b each have the same meaning as above. The positive electrode active material for sodium secondary batteries comprises the mixed metal oxide above. |
申请公布号 |
US9142860(B2) |
申请公布日期 |
2015.09.22 |
申请号 |
US200912865993 |
申请日期 |
2009.02.03 |
申请人 |
SUMITOMO CHEMICAL COMPANY, LIMITED |
发明人 |
Kuze Satoru;Makidera Masami;Yamamoto Taketsugu |
分类号 |
H01M2/16;H01M4/88;H01M10/054;H01M4/58;H01M4/505;H01M4/525;H01M10/42;C01G49/00;C01G53/00 |
主分类号 |
H01M2/16 |
代理机构 |
Sughrue Mion, PLLC |
代理人 |
Sughrue Mion, PLLC |
主权项 |
1. A sodium secondary battery comprising a positive electrode comprising a positive electrode active material, the positive electrode active material comprising a mixed metal oxide comprising Na, Mn and M1 wherein M1 is Fe or Ni, with a Na:Mn:M1 molar ratio being a:(1−b):b wherein a is a value falling within the range of more than 0.5 and less than 1, and b is a value falling within the range of from 0.05 to 0.25, wherein the mixed metal oxide does not include cobalt. |
地址 |
Tokyo JP |