Method for preparing article having uneven microstructure on surface thereof

摘要

A method for preparing an article having an uneven microstructure on a surface thereof, including coating a surface of a mold having an uneven microstructure formed from an anodized alumina oxide on a surface with a release treatment solution including a mold release agent that includes one or more kinds of phosphoric ester compound and the pH of the aqueous solution when extracted with 50 mL of water with respect to 1 g of the mold release agent is 3.0 or more; and interposing an active energy ray curable resin composition including a polymerizable compound, a polymerization initiator, and an internal release agent between the mold and the substrate, and curing the active energy ray curable resin composition by the irradiation with active energy rays to form a cured resin layer having the uneven microstructure transferred on a surface of the substrate.

主权项

1. A method for preparing an article having an uneven microstructure on a surface thereof, comprising the following steps (I) and (II):
(I) a step of coating a surface of a mold having an uneven microstructure formed from an anodized alumina oxide on a surface thereof with a release treatment solution comprising a mold release agent, where the mold release agent consists of one or more (poly)oxyalkylene alkyl phosphoric ester compounds, where the pH of an aqueous solution resulting from extraction of 1 g of the mold release agent with 50 mL of water is 3.0 or more; and (II) a step of, after the step (I), interposing an active energy ray curable resin composition comprising a polymerizable compound, a polymerization initiator, and an internal release agent between the mold and a substrate, and curing the active energy ray curable resin composition by irradiating the composition with active energy rays to form a cured resin layer having the uneven microstructure transferred thereto on the surface of the substrate, thereby obtaining an article having an uneven microstructure on a surface thereof, wherein the (poly)oxyalkylene alkyl phosphoric ester compound is of a formula (1)
(HO)3-n(O═)P[—O—(R2O)m—R1]n  (1) wherein R1 is an alkyl group, R2 is an alkylene group, m is an integer of 1 to 20, and n is an integer of 1 to 3.