Pesticidal compositions and related methods

摘要

A pesticidal composition comprises a compound of formula I or any agriculturally acceptable salt thereof, wherein R1, R2, R4, R5, R6, R7, Z, Q, and Y are as described herein. A method of controlling pests comprises applying the pesticidal composition near a population of pests, or to an area to control pests.;

主权项

1. A pesticidal composition, comprising a compound of formula I or any agriculturally acceptable salt thereof:wherein:
(a) R1, R2, and R4 are independently hydrogen, F, Cl, Br, I, substituted or unsubstituted C1-C6 alkyl, or substituted or unsubstituted C1-C6 haloalkyl or substituted or unsubstituted C1-C10 cycloalkyl, substituted or unsubstituted C1-C10 halocycloalkyl, wherein each said R1, R2, and R4, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, C1-C6 haloalkyl, C3-C10 cycloalkyl, or C3-C10 halocycloalkyl, each of which may be substituted and may optionally be substituted with R10; (b) R3 is hydrogen, F, Cl, Br, I, CN, NO2, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C2-C6 alkynyl, substituted or unsubstituted C1-C6 alkoxy, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C1-C6 haloalkyl, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C1-C20 heterocyclyl, OR10, C(═X1)R10, C(═X1)OR10, C(═X1)N(R10)2, N(R10)2, N(R10)C(═X1)R10, S(O)nR10, S(O)nOR10, or R10S(O)nR10, wherein each said R3, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, C3-C10 halocycloalkenyl, OR10, S(O)nOR10, C6-C20 aryl, or C1-C20 heterocyclyl, each of which is unsubstituted, substituted, or substituted with R10; (c) R5 is selected from hydrogen, F, Cl, Br, I, CN, NO2, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 alkoxy, C3-C10 cycloalkyl, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C1-C20 heterocyclyl, OR10, C(═X1)R10, C(═X1)OR10, C(═X1)N(R10)2, N(R10)2, N(R10)C(═X1)R10, SR10, S(O)nOR10, or R10S(O)nR10, wherein each said R5, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, C3-C10 halocycloalkenyl, OR10, S(O)nOR10, C6-C20 aryl, or C1-C20 heterocyclyl, each of which is unsubstituted, substituted, or substituted with R10; (d) Y is a bond or is substituted or unsubstituted C1-C6 alkyl, or substituted or unsubstituted C2-C6 alkenyl, except where Y is a bond, wherein each Y, when substituted, has one or more substituents selected from hydrogen, F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, or C3-C10 cycloalkyl, optionally Y and R7 may be connected in a cyclic arrangement, where optionally such arrangement may have one or more heteroatoms selected from O, S, or N, in the cyclic structure connecting Y and R7; (e) R6 is selected from hydrogen, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C2-C6 alkynyl, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C1-C20 heterocyclyl, C1-C6 alkyl-(C3-C10 cyclohaloalkyl) wherein the alkyl and cyclohaloalkyl is independently substituted or unsubstituted, or C1-C6 alkyl-(C3-C10 cycloalkyl), wherein the alkyl and cycloalkyl is independently substituted or unsubstituted, wherein each R6, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl C1-C6 haloalkyl, C1-C6 alkoxy, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, C3-C10 halocycloalkenyl, OR10, S(O)nOR10, C6-C20 aryl, C1-C20 heterocyclyl, or R10 aryl, each of which is unsubstituted, substituted, or substituted with R10; (f) R7 is R9, R8S(O)nR9; (g) R8 is substituted or unsubstituted C1-C12 alkenyl, or C1-C12 alkynyl, substituted or unsubstituted C1-C12 alkyl, or substituted or unsubstituted C3-C10 cycloalkyl, wherein each said R8, when substituted, has one or more substituents selected from F, Cl, Br, I, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C3-C10 cycloalkyl, C3-C10 halocycloalkyl, OR10, S(O)nR10, C6-C20 aryl, or C1-C20 heterocyclyl, each of which is unsubstituted, substituted, or substituted with R10; (h) R9 is selected from hydrogen, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 alkoxy, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C3-C10 halocycloalkyl substituted, or unsubstituted C3-C10 cycloalkenyl, substituted or unsubstituted C1-C6 haloalkyl substituted or unsubstituted C6-C20 aryl, or substituted or unsubstituted C1-C20 heterocyclyl, wherein each said R9, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C2-C6 haloalkynyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, C3-C10 halocycloalkenyl, oxo, OR10, S(O)nR10, C6-C20 aryl, or C1-C20 heterocyclyl, each of which is unsubstituted, substituted, or substituted with R10; (i) R10 is selected from hydrogen, CN, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 alkoxy, substituted or unsubstituted C2-C6 alkenyloxy, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C3-C10 cycloalkenyl, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C1-C20 heterocyclyl, substituted or unsubstituted S(O)nC1-C6 alkyl, or substituted or unsubstituted N(C1-C6alkyl)2R8 is substituted or unsubstituted C1-C12 alkenyl, substituted or unsubstituted C1-C12 alkyl, or substituted or unsubstituted C3-C10 cycloalkyl, wherein each said R10, when substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, C3-C10 halocycloalkenyl, OC1-C6 alkyl, OC1-C6 haloalkyl, S(O)nC1-C6alkyl, S(O)nOC1-C6 alkyl, C6-C20 aryl, or C1-C20 heterocyclyl; (j) Q and X1 are independently oxygen (O) or sulfur (S); (k) n is 0, 1, or 2; and (l) Z is N or C—R3.