发明名称 |
Methods for suppressing isomerization of olefin metathesis products |
摘要 |
A method for suppressing isomerization of an olefin metathesis product produced in a metathesis reaction includes adding an isomerization suppression agent to a mixture that includes the olefin metathesis product and residual metathesis catalyst from the metathesis reaction under conditions that are sufficient to passivate at least a portion of the residual metathesis catalyst. The isomerization suppression agent includes (i) a salt and/or an ester of a phosphorous oxo acid, and/or (ii) a derivative of the phosphorous oxo acid in which at least one P—H bond has been replaced by a P—C bond, and/or (iii) a salt and/or an ester of the derivative. Methods of refining natural oils are described. |
申请公布号 |
US9133416(B2) |
申请公布日期 |
2015.09.15 |
申请号 |
US201113335517 |
申请日期 |
2011.12.22 |
申请人 |
Elevance Renewable Sciences, Inc. |
发明人 |
Firth Bruce E.;Kirk Sharon E. |
分类号 |
C11B3/00;C07C7/20;C11B1/10;C11C3/10;C07C51/50;C11B5/00 |
主分类号 |
C11B3/00 |
代理机构 |
|
代理人 |
Dailey Robert S. |
主权项 |
1. A method for suppressing isomerization of an olefin metathesis product, the method comprising:
providing a mixture comprising an olefin metathesis product and residual metathesis catalyst; and adding an isomerization suppression agent to the mixture to passivate at least a portion of the residual metathesis catalyst; wherein the isomerization suppression agent is a phosphite ester. |
地址 |
Woodridge IL US |