| 主权项 |
1. A liquid-crystal (LC) medium comprising a low-molecular-weight, non-polymerizable liquid-crystalline component and a polymerizable or polymerized component comprising one or more polymerizable compounds of formula I, where the polymerized component is obtainable by polymerization of the polymerizable component,
R1-[A3-Z3]m-[A2]k-[Z2]n-A1-Ra (I) in which A1, A2, A3 each, independently of one another, denote an aromatic, heteroaromatic, alicyclic or heterocyclic group, which may also contain fused rings, and which may also be mono- or polysubstituted by a group L or -Sp-P, L in each case, independently of one another, denotes H, F, Cl, Br, I, —CN, —NO2, —NCO, —NCS, —OCN, —SCN, —C(═O)N(R0)2, —C(═O)R0, optionally substituted silyl, optionally substituted aryl or cycloalkyl having 3 to 20 C atoms, or straight-chain or branched alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylcarbonyloxy or alkoxycarbonyloxy having 1 to 25 C atoms, in which, in addition, one or more H atoms may each be replaced by F or Cl, P denotes a polymerizable group, Sp denotes a spacer group or a single bond, Z2 in each case, independently of one another, denotes —O—, —S—, —CO—, —CO—O—, —OCO—, —O—CO—O—, —OCH2—, —CH2O—, —SCH2—, —CH2S—, —CF2O—, —OCF2—, —CF2S—, —SCF2—, —(CH2)n1—, —CF2CH2—, —CH2CF2—, —(CF2)n1—, —CH═CH—, —CF═CF—, —C≡C—, —CH═CH—COO—, —OCO—CH═CH—, —(CR0R00)n1—, —CH(-Sp-P)—, —CH2CH(-Sp-P)—, or —CH(-Sp-P)CH(-Sp-P)—, Z3 in each case, independently of one another, denotes a single bond, —O—, —S—, —CO—, —CO—O—, —OCO—, —O—CO—O—, —OCH2—, —CH2O—, —SCH2—, —CH2S—, —CF2O—, —OCF2—, —CF2S—, —SCF2—, —(CH2)n1—, —CF2CH2—, —CH2CF2—, —(CF2)n1—, —CH═CH—, —CF═CF—, —C≡C—, —CH═CH—COO—, —OCO—CH═CH—, —(CR0R00)n1—, —CH(-Sp-P)—, —CH2CH(-Sp-P)—, or —CH(-Sp-P)CH(-Sp-P)—, n1 denotes 1, 2, 3 or 4, n denotes 0 or 1, m denotes 0, 1, 2, 3, 4, 5 or 6, k denotes 0 or 1, R0 in each case, independently of one another, denotes alkyl having 1 to 12 C atoms, R00 in each case, independently of one another, denotes H or alkyl having 1 to 12 C atoms, R1, independently of one another, denotes H, halogen, straight-chain, branched or cyclic alkyl having 1 to 25 C atoms, in which, in addition, one or more non-adjacent CH2 groups may each be replaced by —O—, —S—, —CO—, —CO—O—, —O—CO—, or —O—CO—O— in such a way that O and/or S atoms are not linked directly to one another and in which, in addition, one or more H atoms may each be replaced by F or Cl,
or a group -Sp-P, Ra denotes an anchor group of the formula p denotes 1 or 2, q denotes 2 or 3, B denotes a substituted or unsubstituted ring system or condensed ring system, Y, independently of one another, denotes —O—, —S—, —C(O)—, —C(O)O—, —OC(O)—, —NR11— or a single bond, o denotes 0 or 1, X1, independently of one another, denotes H, alkyl, fluoroalkyl, OH, NH2, NHR11, NR112, OR11, C(O)OH, —CHO,
where at least one group X1 denotes a radical selected from —OH, —NH2, NHR11, C(O)OH and —CHO, R11 denotes alkyl having 1 to 12 C atoms, Spa, Spc, Spd each, independently of one another, denote a spacer group or a single bond, and Spb denotes a tri- or tetravalent group, where the compound of the formula I contains at least one polymerizable group P within the groups A1, A2, A3, Z2 and Z3, as are present. |
