METHOD FOR MANUFACTURING A WHOLLY AROMATIC POLYIMIDE RESIN HAVING IMPROVED HEAT RESISTANCE AND ELONGATION PROPERTIES IN A HIGH TEMPERATURE RANGE

摘要

The present invention relates to a method for preparing wholly aromatic polyimide resin with improved heat-resistance. In particular, the present invention provides a method for preparing polyimide resin having enhanced heat-resistance and superior mechanical properties, especially elongation rate and tensile strength at high temperature through liquid polymerization of two kinds of aromatic tetracarboxylic dianhydrides and aromatic diamine whose mixed ratio is properly regulated. Since the polyimide prepared according to the method of the present invention exhibits high heat-resistance and improved ensile strength and elongation rate at high temperature while maintaining intrinsic properties of polyimide, it can be used as a core heat-resistant material of semiconductor and aerospace fields where higher heat-resistance and mechanical properties are required.