| 发明名称 |
PROCESS FOR PHOTOCATALYTIC ACCEPTOR-FREE DEHYDROGENATION OF HYDROCARBAZOLES AND HYDROINDOLES |
| 摘要 |
A process for the photocatalytic acceptor-free dehydrogenation of hydrocarbazoles and hydroindoles is provided, wherein a hydrocarbazole or hydroindole is irradiated in the presence of a catalyst that is a rhodium complex containing organic phosphorus(III) compounds as ligands. |
| 申请公布号 |
US2015239839(A1) |
申请公布日期 |
2015.08.27 |
| 申请号 |
US201514629095 |
申请日期 |
2015.02.23 |
| 申请人 |
FRANKE Robert;JULIS Jennifer;FRIDAG Dirk;DYBALLA Katrin Marie;WEDING Nico;CHOWDHURY Abhishek Dutta;BELLER Matthias;JACKSTELL Ralf;FLEISCHER Ivana;PERCIA Beatrice |
发明人 |
FRANKE Robert;JULIS Jennifer;FRIDAG Dirk;DYBALLA Katrin Marie;WEDING Nico;CHOWDHURY Abhishek Dutta;BELLER Matthias;JACKSTELL Ralf;FLEISCHER Ivana;PERCIA Beatrice |
| 分类号 |
C07D209/86 |
主分类号 |
C07D209/86 |
| 代理机构 |
|
代理人 |
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| 主权项 |
1. A process for dehydrogenation of a hydrocarbazole or a hydroindole, comprising:
irradiating the hydrocarbazole or hydroindole in a reaction mixture comprising a rhodium complex to remove hydrogen from the hydrocarbazole or hydroindole; wherein a hydrogen acceptor is not present, and the rhodium complex comprises a ligand of an organic phosphorus(III) compound. |
| 地址 |
Marl DE |
