| 发明名称 |
PROCESS FOR PHOTOCATALYTIC ACCEPTOR-FREE DEHYDROGENATION OF ALKANES AND ALCOHOLS |
| 摘要 |
A process for photocatalytic acceptor-free dehydrogenation of alkanes and alcohols, in which an alkane or an alcohol is irradiated in the presence of a rhodium complex containing organic phosphorus(III) compounds as ligands as a catalyst, and in the presence of at least one Lewis base is provided. |
| 申请公布号 |
US2015239814(A1) |
申请公布日期 |
2015.08.27 |
| 申请号 |
US201514630018 |
申请日期 |
2015.02.24 |
| 申请人 |
FRANKE Robert;Julis Jennifer;Fridag Dirk;Dyballa Katrin Marie;Weding Nico;Chowdhury Abhishek Dutta;Beller Matthias;Jackstell Ralf;Fleischer Ivana;Percia Beatrice |
发明人 |
FRANKE Robert;Julis Jennifer;Fridag Dirk;Dyballa Katrin Marie;Weding Nico;Chowdhury Abhishek Dutta;Beller Matthias;Jackstell Ralf;Fleischer Ivana;Percia Beatrice |
| 分类号 |
C07C45/00;C07C5/333 |
主分类号 |
C07C45/00 |
| 代理机构 |
|
代理人 |
|
| 主权项 |
1. A process for dehydrogenation of an alkane or an alcohol, comprising:
irradiating the alkane or alcohol in a reaction mixture comprising a rhodium complex and a Lewis base to remove hydrogen from the alkane or alcohol; wherein a hydrogen acceptor is not present, and the rhodium complex comprises a ligand of an organic phosphorus(III) compound. |
| 地址 |
Marl DE |
