发明名称 |
INCREASED POLYMER MELT FLOW RATIO VIA FEED OF A SUPPORTED CATALYST SATURATED WITH A SELECTED LIQUID AGENT |
摘要 |
A process for the production of ethylene alpha- olefin copolymers is disclosed. The process may include feeding a catalyst system comprising a supported metallocene , such as a hafnocene, having pores saturated with a selected liquid agent, to a gas phase polymerization reactor. Ethylene and an alpha- olefin may then be contacted with the supported metallocene in the gas phase polymerization reactor to produce an ethylene alpha- olefin copolymer. The copolymer may have a density of less than 0.93 g/cm3' a melt index (3/4 of less than 2 dg/min, and a melt flow ratio (I21 / 12) of at least 28. To advantageously result in desired effects on catalyst properties and/or polymer properties, the liquid agent may be selected to advantageously manipulate catalyst temperature profiles and/or catalyst - monomer interaction during an initial heating period when the catalyst is first introduced to the reactor. |
申请公布号 |
IN10082DEN2014(A) |
申请公布日期 |
2015.08.21 |
申请号 |
IN2014DELNP10082 |
申请日期 |
2014.11.27 |
申请人 |
UNIVATION TECHNOLOGIES LLC |
发明人 |
HUSSEIN ,F., DAVID;ZILKER, DANIEL ,P.;CANN ,KEVIN, J. |
分类号 |
C08F210/02;C08F2/34;C08F4/64 |
主分类号 |
C08F210/02 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|