发明名称 CURABLE RESIN COMPOSITION AND SHORT-CURE METHOD
摘要 Disclosed herein is a method for utilizing the exothermic energy generated by a low temperature cure reaction to access a high-temperature cure reaction, which is otherwise energetically inaccessible at a chosen tool temperature, thereby producing a cured resin matrix with properties closely matching to those produced via high-temperature cure reactions but achieved via a short cure time and low cure temperature. Also disclosed is a short-cure resin composition containing: (a) at least one multifunctional epoxy resin having an epoxy functionality of greater than 1; (b) a hardener composition containing (i) at least one aliphatic or cycloaliphatic amine curing agent having one or more amino groups per molecule; (ii) at least one aromatic amine curing agent having one or more amino groups per molecule; and optionally, (iii) an imidazole as curing accelerator. The improved properties of this resin composition include being curable at a temperature of ≦120° C. for a time period of less than 10 minutes to achieve a degree of cure higher than that derived from the same composition with just (i) aliphatic/cycloaliphatic amine or (ii) aromatic amine in isolation.
申请公布号 US2015218345(A1) 申请公布日期 2015.08.06
申请号 US201514686847 申请日期 2015.04.15
申请人 CYTEC TECHNOLOGY CORP. 发明人 Meegan Jonathan E.
分类号 C08K7/06;B29C70/48;C08G59/00 主分类号 C08K7/06
代理机构 代理人
主权项 1. A curable epoxy resin composition having a viscosity suitable for Resin Transfer Molding (RTM), said composition comprising: (a) at least one multifunctional epoxy resin having an epoxy functionality of greater than 1 and that functionality is based on glydicyl amine, or glycidyl ether, or both; (b) a hardener composition comprising: i. at least one aliphatic or cycloaliphatic amine curing agent having one or more amino groups per molecule and capable of individually initiating a curing reaction of said at least one multifunctional epoxy resin at a cure onset temperature within the range of 30° C.-100° C. and selected from a group consisting of: isophorone diamine, triethylamine, diethylamine, triethylenetetramine (TETA), and Polyether amines;ii. at least one aromatic amine curing agent having one or more amino groups per molecule and capable of individually initiating a curing reaction of said at least one multifunctional epoxy resin at a cure onset temperature of 120° C. or greater and selected from a group consisting of, but not limited to: 3,3′diaminodiphenylsulphone, 4,4′diaminodiphenylsulphone; 4,4′-methylene-bis-(3-chloro-2,6-diethylaniline) (MCDEA), 4,4′-methylene-bis-(2,6-diethylaniline) (MDEA), 2,6-diethylaniline (DEA), and dianiline; and (c) optionally, an imidazole as curing accelerator, wherein, per 100 parts of multifunctional epoxy resin (a), the amount of hardener composition (b) is 10-90 parts, and if present, the amount of imidazole (c) is up to 10 parts, and wherein said epoxy resin composition is curable at a temperature below the cure onset temperature of the aromatic amine curing agent for a time period of less than 5 minutes to achieve a degree of cure of 95% or higher.
地址 Wilmington DE US