发明名称 AZAINDOLE CARBOXYLIC ACID AMIDES AND AZAINDOLE THIOCARBOXYLIC ACID AMIDES FOR USE AS INSECTICIDES AND ACARICIDES
摘要 The present invention relates to compounds of the general formula (I);;in which R1 to R6, A, Y, X, Q1, Q2, n and m are each as defined in the description and to a process for their preparation and to their use as insecticides and acaricides.
申请公布号 US2015216175(A1) 申请公布日期 2015.08.06
申请号 US201314421848 申请日期 2013.08.13
申请人 BAYER CROPSCIENCE AG 发明人 Heil Markus;Andree Roland;Heilmann Eike Kevin;Jeschke Peter;Riedrich Matthias;Iig Kerstin;Görgens Ulrich;Voerste Arnd
分类号 A01N53/00;A01N43/90 主分类号 A01N53/00
代理机构 代理人
主权项 1. A compound of formula (I) where R1 represents halogen, nitro, cyano, amino, hydroxy, represents C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, C1-C6-alkoxy, (C1-C6-alkoxy)carbonyl, C1-C6-alkylamino, formyl, (C1-C6-alkyl)carbonyl, C1-C6-alkoxyimino-C1-C6-alkyl, C1-C6-dialkylamino, (C1-C6-alkylamino)carbonyl, (C1-C6-dialkylamino)carbonyl, C1-C6-alkylthio, C1-C6-alkylsulphinyl, C1-C6-alkylsulphonyl, C1-C6-alkylaminosulphonyl, C1-C6-alkylsulphonylamino which are optionally mono- or polysubstituted by identical or different substituents, where the substituents are independently of one another selected from the group consisting of halogen, cyano, nitro, C1-C6-alkyl, C1-C6-alkoxy and C1-C6-haloalkoxy, n represents 1, 2, 3, 4 or 5, or R1 represents —OCF2O—, —(CF2)2O— or —O(CF2)2O— and is attached to two adjacent carbon atoms, in which case n represents 1, R2 represents hydrogen or represents C1-C4-alkyl which is optionally mono- or polysubstituted by identical or different substituents, where the substituents are independently of one another selected from the group consisting of halogen and C1-C4-alkyl, R3 represents hydrogen, represents C1-C4-alkyl, C1-C4-alkylcarbonyl, or C1-C4-alkoxycarbonyl which are optionally mono- or polysubstituted by identical or different substituents, where the substituents are each independently selected from cyano, halogen, C1-C4-alkyl and C1-C4-alkoxy, R4 represents C1-C6-alkyl, C2-C6-alkenyl, C3-C6-alkynyl, C3-C6-cycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl or aryl-C1-C4-alkyl which are optionally mono- or polysubstituted by identical or different substituents, where the substituents are each independently selected from halogen, cyano, C1-C4-alkyl and C1-C4-alkoxy, C1-C4-alkoxycarbonyl and from optionally singly or multiply, identically or differently substituted aryloxy and aryl-C1-C3-alkoxy,where the substituents are each independently selected from halogen, cyano, C1-C4-alkyl, C1-C4-alkoxy, R5 represents hydrogen, C1-C4-alkyl, halogen or cyano, R6 represents hydrogen, halogen, nitro, cyano, amino, hydroxy, represents C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, C1-C6-alkoxy, (C1-C6-alkoxy)carbonyl, C1-C6-alkylamino, formyl, (C1-C6-alkyl)carbonyl, C1-C6-alkoxyimino-C1-C6-alkyl, C1-C6-dialkylamino, (C1-C6-alkylamino)carbonyl, (C1-C6-dialkylamino)carbonyl, C1-C6-alkylthio, C1-C6-alkylsulphinyl, C1-C6-alkylsulphonyl, C1-C6-alkylaminosulphonyl, C1-C6-alkylsulphonylamino, aryl, hetaryl, aryl-C1-C4-alkyl or hetaryl-C1-C4-alkyl which are optionally mono- or polysubstituted by identical or different substituents, where the substituents are independently of one another selected from the group consisting of halogen, cyano, nitro, hydroxy, amino, C1-C6-alkyl, C1-C6-alkoxy, C3-C6-cycloalkyl, C1-C6-haloalkoxy, C1-C6-alkylthio, aryl, hetaryl, arylalkyl, hetarylalkyl,where the substituents aryl, hetaryl, arylalkyl, hetarylalkyl are optionally mono- or polysubstituted by identical or different substituents from the group consisting of halogen, cyano, nitro, hydroxy, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, C1-C6-alkoxy, C1-C6-haloalkyl, C1-C6-haloalkoxy and C1-C6-alkylthio, m represents 0, 1 or 2, X represents C1-C6-haloalkyl which may optionally additionally be mono- to trisubstituted, where the substituents are independently of one another selected from the group consisting of hydroxy, cyano and C1-C4-alkoxy, W represents O or S, A represents a bivalent chemical moiety which is selected from the —C(R11)(R12)NR13C(═O)—, —C(═O)NR13—, —C(═S)NR13—, —C(R11)(U)NR13C(═O)—, —C(R11)(R12)N(U)C(═O)—, —N(R11)NR13C(═O)— moieties, where the first (left-hand) point of attachment in each case connects to the ring and the second (right-hand) point of attachment in each case connects to Y, and where U represents optionally substituted C2-C4-alkyl which, together with a carbon atom adjacent to the point of attachment of A at the ring forms a 5- to 7-membered ring, where the substituents are independently of one another selected from the group consisting of C1-C4-alkyl and C1-C4-alkoxy, R11 and R12 are each independently hydrogen or C1-C4-alkyl, R13 represents hydrogen, represents C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-alkylcarbonyl, C1-C4-alkoxycarbonyl or C1-C4-alkenyl, Y represents C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, heterocyclyl, oxido-heterocyclyl, dioxido-heterocyclyl, aryl, aryl-C1-C4-alkyl, hetaryl or hetaryl-C1-C4-alkyl which are optionally mono- or polysubstituted by identical or different substituents, where the substituents are selected from the group consisting of halogen, nitro, cyano, hydroxy, aminothiocarbonyl, aminocarbonyl, C1-C4-alkylaminocarbonyl, C1-C4-haloalkylaminocarbonyl, di(C1-C4-alkyl)aminocarbonyl, hydroxycarbonyl, C1-C4-alkyl, C1-C4-halo alkyl, C3-C6-cycloalkyl, C1-C4-alkyl-C3-C4-cycloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylcarbonyl, C1-C4-alkoxyimino-C1-C4-alkyl, C1-C6-alkylthio, C1-C6-alkylsulphinyl and C1-C6-alkylsulphonyl, Q1 represents N, where simultaneously Q2 represents a carbon atom which is substituted by hydrogen, R6 or A-Y, or Q1 represents a carbon atom which is substituted by hydrogen, R6 or A-Y and Q2 simultaneously represents N, and also salts and N-oxides of compounds of the formula (I).
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