摘要 |
We report a new class of single-ion electrolyte including pendant lithium perfluoroethyl sulfonates. Embodiments may be based on, for example, aromatic poly(arylene ether)s, polyphenylenes, or polyarylene sulfides. The microporous polymer film saturated with organic carbonates exhibits a nearly unity tLi+, state-of-the-art conductivities (e.g. >10−3 S cm−1 at room temperature) over a wide range of temperatures, high electrochemical stability, and outstanding mechanical properties, which enables the membrane to function as both ion conducting medium and separator in the batteries. |