发明名称 |
Method for producing alicyclic carboxylic acid and catalyst used in same |
摘要 |
Provided is a method for producing an alicyclic carboxylic acid by hydrogenating an aromatic ring of an aromatic carboxylic acid, which comprises using a catalyst containing ruthenium and palladium as a catalyst, and also provided is a co-supported ruthenium-palladium catalyst in which ruthenium and palladium are present in a form of particles containing both the ruthenium and palladium on a surface of a support. A catalyst has been developed which uses a relatively inexpensive noble metal, ruthenium, which has an activity equivalent to that of a rhodium catalyst, and which does not undergo decrease in activity as observed in a rhodium catalyst, and thereby an industrially simple method for producing an alicyclic carboxylic acid has been established. |
申请公布号 |
US9084985(B2) |
申请公布日期 |
2015.07.21 |
申请号 |
US201214002602 |
申请日期 |
2012.02.24 |
申请人 |
MITSUBISHI GAS CHEMICAL COMPANY, INC. |
发明人 |
Iida Akifumi;Watanabe Ryoko;Tsujimoto Tomoo |
分类号 |
C07C51/36;B01J23/63;B01J21/04;B01J23/46;B01J21/06;B01J21/08;B01J21/18;B01J37/02 |
主分类号 |
C07C51/36 |
代理机构 |
Oblon, McClelland, Maier & Neustadt, L.L.P. |
代理人 |
Oblon, McClelland, Maier & Neustadt, L.L.P. |
主权项 |
1. A method for producing an alicyclic carboxylic acid, the method comprising:
hydrogenating an aromatic ring of an aromatic carboxylic acid in the presence of a catalyst in water, wherein the aromatic carboxylic acid is selected from the group consisting of trimellitic acid, trimesic acid and pyromellitic acid; and the catalyst is a catalyst in which ruthenium and palladium are co-supported on a support. |
地址 |
Tokyo JP |