发明名称 Method for producing alicyclic carboxylic acid and catalyst used in same
摘要 Provided is a method for producing an alicyclic carboxylic acid by hydrogenating an aromatic ring of an aromatic carboxylic acid, which comprises using a catalyst containing ruthenium and palladium as a catalyst, and also provided is a co-supported ruthenium-palladium catalyst in which ruthenium and palladium are present in a form of particles containing both the ruthenium and palladium on a surface of a support. A catalyst has been developed which uses a relatively inexpensive noble metal, ruthenium, which has an activity equivalent to that of a rhodium catalyst, and which does not undergo decrease in activity as observed in a rhodium catalyst, and thereby an industrially simple method for producing an alicyclic carboxylic acid has been established.
申请公布号 US9084985(B2) 申请公布日期 2015.07.21
申请号 US201214002602 申请日期 2012.02.24
申请人 MITSUBISHI GAS CHEMICAL COMPANY, INC. 发明人 Iida Akifumi;Watanabe Ryoko;Tsujimoto Tomoo
分类号 C07C51/36;B01J23/63;B01J21/04;B01J23/46;B01J21/06;B01J21/08;B01J21/18;B01J37/02 主分类号 C07C51/36
代理机构 Oblon, McClelland, Maier & Neustadt, L.L.P. 代理人 Oblon, McClelland, Maier & Neustadt, L.L.P.
主权项 1. A method for producing an alicyclic carboxylic acid, the method comprising: hydrogenating an aromatic ring of an aromatic carboxylic acid in the presence of a catalyst in water, wherein the aromatic carboxylic acid is selected from the group consisting of trimellitic acid, trimesic acid and pyromellitic acid; and the catalyst is a catalyst in which ruthenium and palladium are co-supported on a support.
地址 Tokyo JP