发明名称 |
One-pot synthesis of Nb2O5-doped TiO2 nanoparticles |
摘要 |
A one-pot synthesis of Nb 5 +-doped TiO 2 nanoparticles (NPs) with low cost and high efficiency for dye sensitized solar cells (DSSCs) is disclosed in the present invention. The Nb 5+ -doped TiO 2 NPs with Nb dopants of 0-5 mol% are prepared by directly mixing TiO 2 slurry with Nb 2 O 5 gel obtained by UV treatment of a mixture of NbCl 5 powder, ethanol and water in a certain ratio, following by heat treatment without using hydrothermal method. The as-prepared NPs exhibit well-crystallized pure anatase TiO 2 phase with uniform particle distribution. The incorporation of Nb 5+ leads to a stronger and broader light absorption in visible light range and a decrease of band gap with increasing Nb dopant content, which enhances the efficiencies of light-harvesting and electron injection and suppresses the charge recombination. The present method provides a simple and cost-effective mass-production route to synthesize n-type metallic ion doped TiO 2 nanoparticles as excellent photoanode materials. |
申请公布号 |
EP2894129(A1) |
申请公布日期 |
2015.07.15 |
申请号 |
EP20140161905 |
申请日期 |
2014.03.27 |
申请人 |
NANO AND ADVANCED MATERIALS INSTITUTE LIMITED |
发明人 |
FENG, SHIEN-PING;SU, HAIJUN;CHANG, YA-HUEI;HUANG, YU-TING;HAU, NGA YU;ZHAI, PENG |
分类号 |
C01G23/08;C01G33/00;C09C1/36;H01G9/20 |
主分类号 |
C01G23/08 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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