发明名称 Titanium oxide particles, process for producing same, magnetic memory, optical information recording medium, and charge accumulation type memory
摘要 A titanium oxide particle that can develop non-conventional and novel physical properties, a method for manufacturing the same, and a magnetic memory, an optical information recording medium, and a charge accumulation type memory using the same are provided. A silica-coated titanium hydroxide compound particle is directly produced through a sol-gel technique and not through a reverse micelle technique, and the silica-coated titanium hydroxide compound particle is subjected to a calcination process. Hence, a titanium oxide particle 1 can be provided which can develop non-conventional and novel physical properties such that it does not perform phase transition at a room temperature and a Ti3O5 particle body can always maintain the characteristic as a paramagnetic metal in all temperature ranges unlike conventional bulk bodies that perform phase transition between a non-magnetic semiconductor and a paramagnetic metal at a temperature near about 460 K.
申请公布号 US9079782(B2) 申请公布日期 2015.07.14
申请号 US201113699082 申请日期 2011.04.15
申请人 The University of Tokyo 发明人 Ohkoshi Shin-ichi;Tokoro Hiroko;Hakoe Fumiyoshi;Tsunobuchi Yoshihide;Hashimoto Kazuhito
分类号 C01G23/00;C01G23/04;C09C1/36;B82Y10/00;B82Y25/00;B82Y40/00;H01L21/28;H01L43/10;B82Y30/00 主分类号 C01G23/00
代理机构 Locke Lord LLP 代理人 Locke Lord LLP ;Armstrong, IV James E.
主权项 1. A method for producing a titanium oxide particle comprising: a step of mixing a titanium chloride aqueous solution with an ammonium aqueous solution to prepare a mixture solution and produce a titanium hydroxide compound particle by a hydroxylation reaction in a water phase of a mixture solution; a step of adding a silane compound to the mixture solution to produce a silica-coated titanium hydroxide compound particle; and a step of calcining the silica-coated titanium hydroxide compound particle separated from the mixture solution under a hydrogen atmosphere to produce a Ti3O5 particle body in a microparticle shape which is coated with silica glass.
地址 Tokyo JP