发明名称 Process for the preparation of hydrogenated nitrile rubber
摘要 The present invention relates to a process for the production of hydrogenated nitrile rubber polymers having lower molecular weights and narrower molecular weight distributions than those known in the art, wherein the process is carried out in the presence of hydrogen and optionally at least one co-olefin. The present invention further relates to the use of specific metal compounds in a process for the production of a hydrogenated nitrile rubber by simultaneous hydrogenation and metathesis of a nitrile rubber.
申请公布号 US9079979(B2) 申请公布日期 2015.07.14
申请号 US201013391633 申请日期 2010.08.27
申请人 LANXESS DEUTSCHLAND GMBH 发明人 Ong Christopher;Mueller Julia Maria
分类号 C08C19/02;B01J31/18;B01J31/22;C08C19/08;C08L15/00;C08C19/00 主分类号 C08C19/02
代理机构 代理人
主权项 1. A process for the production of a hydrogenated nitrile rubber, the process comprising simultaneously hydrogenating and metathesizing nitrite rubber in the presence of hydrogen, at least one catalyst, and optionally at least one co-olefin, wherein each at least one catalyst is capable of catalyzing both the hydrogenating and metathesizing, and catalyzes the hydrogenating and metathesizing of the nitrite rubber, and each at least one catalyst is selected from the group consisting of compounds of general formulae (I), (II) or (Ill), where M is ruthenium or osmium, X1 and X2 are identical or different anionic ligands, Z1 and Z2 are identical or different neutral electron donor ligands, R3 and R4 are each independently hydrogen or a substituent selected from the group consisting of alkyl, cycloalkyl, alkenyl, alkynyl, aryl, carboxylate, alkoxy, alkenyloxy, alkynyloxy, aryloxy, alkoxycarbonyl, alkylamino, alkylthio, arylthio, alkylsulphonyl and alkylsulphinyl radical, each of which may optionally be substituted by one or more alkyl, halogen, alkoxy, aryl or heteroaryl radicals, and L is a ligand.
地址 Cologne DE