发明名称 PREPREG AND CARBON FIBER REINFORCED COMPOSITE MATERIAL
摘要 A prepreg is formed by impregnating sizing agent-coated carbon fibers coated with a sizing agent with a thermosetting resin composition. The sizing agent contains an aliphatic epoxy compound (A) and an aromatic compound (B) at least containing an aromatic epoxy compound (B1). The sizing agent-coated carbon fibers has an (a)/(b) ratio of 0.50 to 0.90 where (a) is a height (cps) of a component at a binding energy (284.6 eV) assigned to CHx, C—C, and C═C and (b) is a height (cps) of a component at a binding energy (286.1 eV) assigned to C—O in a C1s core spectrum of a surface of the sizing agent applied onto the carbon fibers analyzed by X-ray photoelectron spectroscopy using AlKα1,2 as an X-ray source at a photoelectron takeoff angle of 15°.
申请公布号 US2015184333(A1) 申请公布日期 2015.07.02
申请号 US201314416234 申请日期 2013.07.16
申请人 TORAY INDUSTRIES, INC. 发明人 Arai Nobuyuki;Ichikawa Tomoko;Taiko Hiroshi;Endo Makoto;Kobayashi Masanobu;Misumi Jun
分类号 D06M15/55;C08K7/06;C08L63/00;C08J5/24 主分类号 D06M15/55
代理机构 代理人
主权项 1. A prepreg formed by impregnating sizing agent-coated carbon fibers coated with a sizing agent with a thermosetting resin composition, wherein the sizing agent contains an aliphatic epoxy compound (A) and an aromatic compound (B) at least containing an aromatic epoxy compound (B1), the sizing agent-coated carbon fibers has an (a)/(b) ratio of 0.50 to 0.90 where (a) is a height (cps) of a component at a binding energy (284.6 eV) assigned to CHx, C—C, and C═C and (b) is a height (cps) of a component at a binding energy (286.1 eV) assigned to C—O in a C1s core spectrum of a surface of the sizing agent applied onto the carbon fibers analyzed by X-ray photoelectron spectroscopy using AlK□1,2 as an X-ray source at a photoelectron takeoff angle of 15°, the thermosetting resin composition contains a thermosetting resin (D), a latent curing agent (E), and at least one of the following [1] and [2]: [1] thermoplastic resin particles or fibers (F) and conductive particles or fibers (G); and[2] conductive particles or fibers (H) whose thermoplastic resin nucleus or core is covered with a conductive substance, when containing [1], the thermosetting resin composition contains the thermoplastic resin particles or fibers (F) and the conductive particles or fibers (G) in a mass ratio of 1:1 to 1,000, and the prepreg includes an interlayer formative layer containing (F) and (G) and/or (H) on a surface of a layer formed of the carbon fibers.
地址 Tokyo JP