发明名称 |
Fluorine rubber composition and bladder for tire production |
摘要 |
A fluorine rubber composition that provides high tensile strength and high elongation after vulcanization mutually compatible and from which favorable mechanical characteristics are obtained even in a high-temperature environment; and a bladder for tire production, which is manufactured using the same are provided. The fluorine rubber composition includes a rubber component containing a fluorine rubber and carbon black, wherein the carbon black has a specific surface area by nitrogen adsorption (N2SA) of 25 m2/g or more and not more than 180 m2/g and a dibutyl phthalate (DBP) absorption amount of 60 mL/100 g or more and not more than 180 mL/100 g; and in a kneading step (A) of compounding the carbon black in the rubber component, an average shear rate of a rotor surface of a kneading machine is 100 (1/sec) or more, and a kneading maximum temperature Tm is 120° C. or higher and not higher than 200° C. |
申请公布号 |
US9068064(B2) |
申请公布日期 |
2015.06.30 |
申请号 |
US201013817894 |
申请日期 |
2010.08.25 |
申请人 |
BRIDGESTONE CORPORATION;E.I. DU PONT DE NEMOURS AND COMPANY;DAIKEN INDUSTRIES, LTD. |
发明人 |
Yano Masashi;Ota Daisuke;Okutsu Shuichi |
分类号 |
C08L15/02;C08L27/16;B29D22/02;B29D30/06;B29D30/66;C08K5/00 |
主分类号 |
C08L15/02 |
代理机构 |
Oliff PLC |
代理人 |
Oliff PLC |
主权项 |
1. A fluorine rubber composition comprising a rubber component comprising:
a fluorine rubber; carbon black; and a vulcanization system compounding agent containing a co-crosslinking agent, wherein the carbon black has a specific surface area by nitrogen adsorption (N2SA) of 25 m2/g or more and not more than 180 m2/g and a dibutyl phthalate (DBP) absorption amount of 60 mL/100 g or more and not more than 180 mL/100 g; the fluorine rubber is at least one member selected among (A) a copolymer of tetrafluoroethylene/perfluoroalkyl vinyl ether, (B) a copolymer of tetrafluoroethylene/propylene, and (C) a copolymer made of (i) at least one monomer selected among tetrafluoroethylene, hexafluoropropene, pentafluoropropene, trifluoroethylene, chlorotrifluoroethylene, vinyl fluoride, perfluoroalkyl vinyl ether and propylene, and (ii) vinylidene fluoride; and in a kneading step of compounding the carbon black in the rubber component, an average shear rate of a rotor tip point of a kneading machine is 100 (1/sec) or more, and a kneading maximum temperature Tm is 120° C. or higher and not higher than 200° C., wherein the elongation at break at 25° C. of the fluorine rubber composition after vulcanization is 400% or more and not more than 800%, and wherein a compounding amount of the co-crosslinking agent is 0.1 to 2.5 parts by mass based on 100 parts by mass of the rubber component. |
地址 |
Tokyo JP |