发明名称 |
POSITIVE COMPOSITION FOR LITHIUM SECONDARY BATTERY USING SPHERICAL MIXED METAL CARBONATE WITH NANO-TITANATE AND MANUFACTURING METHOD THEREOF |
摘要 |
The present invention relates to a positive electrode material for a non-aqueous lithium secondary battery using a spherical transition metal carbonate complex and a manufacturing method thereof. The present invention improves structural stability of a final positive electrode material by coating the surface of the spherical transition metal carbonate complex with nano-sized metal oxide and obtains excellent life property while obtaining high capacity of 250mAh/g or more. According to the present invention, the spherical transition metal carbonate complex produced by using cobalt raw materials, nickel raw material, manganese raw material, and ammonium carbonate-based raw materials is coated with titanium dioxide, and the transition metal carbonate complex coated with transition metal oxide with a particle size of 5-25 μm having composition of NixCoyMn1-x-yTizCO3(0.0<x<=0.3, 0.0<=y<=0.2, 0.01<=z<=0.1, 0.5<=1-x-y) can be produced. The coated transtion metal carbonate complex is mixed and heat-processed with the lithium raw material so that spherical Li-rich positive electrode material, capable of using 96% or more of an initial capacity after 60 times charge-discharge in a full cell and having 200nm or more and 0.1C capacity of 250mAh/g or more of a primary particle size, can be produced. |
申请公布号 |
KR20150070888(A) |
申请公布日期 |
2015.06.25 |
申请号 |
KR20130157608 |
申请日期 |
2013.12.17 |
申请人 |
KOREA ELECTRONICS TECHNOLOGY INSTITUTE |
发明人 |
SONG, JUN HO;KIM, YOUNG JUN;KIM, JEOM SOO;CHO, WOO SUK;WOO, SANG GIL;YIM, TAE EUN;LEE, KYUNG JUN;PARK, YEONG GWANG |
分类号 |
H01M4/525;H01M4/13;H01M4/505 |
主分类号 |
H01M4/525 |
代理机构 |
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