发明名称 RHODIUM CATALYST AND METHOD FOR MANUFACTURING OPTICALLY ACTIVE COMPOUND USING THE SAME
摘要 PROBLEM TO BE SOLVED: To provide a new rhodium complex stable in the air, easy in handling and using an inexpensive optically active H-phosphinate HP(O)R(OR') as a ligand, and a method for asymmetrically hydrogenating olefins efficiently using the same.SOLUTION: The rhodium complex compound has a structure represented by the following general formula (I). (Where in the formula (I), Rand Rare carbon substituents which may be the same or different, and two olefins coordinated in Rh may combine with each other as shown by a dotted line to form a ring structure.)
申请公布号 JP2015113319(A) 申请公布日期 2015.06.22
申请号 JP20130258070 申请日期 2013.12.13
申请人 NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY 发明人 HAN LI-BIAO ; WANG XIANG-BO
分类号 C07F9/32;B01J31/22;B01J37/04;C07B53/00;C07C13/263;C07C231/18;C07C233/47;C07C309/06;C07F9/40;C07F9/53;C07F15/00 主分类号 C07F9/32
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