发明名称 |
Spinel structured catalyst for aldehyde production |
摘要 |
The present invention refers to a catalyst for aldehyde production, in particular formaldehyde or acetaldehyde production, through selective oxidation of alkanol, especially methanol or ethanol, with oxygen, said catalyst having a spinel structure. The catalyst typically comprises a Fea+qVb+xMoc+yΔzO4 spinel structure wherein Δ is an optional cation vacancy and wherein z=3−q−x−y and q×a+x×b+y×c=8 in concentrations corresponding to 0.6<q<3, 0≦x<1.5, 0≦y≦1 and 0≦z<1.3 and 2≦a≦3, 3≦b≦5 and 3≦c≦6. The present invention further refers to a process for producing said catalyst and to the use of said catalyst for selective oxidation of alkanol, preferably methanol or ethanol, with oxygen to aldehyde, preferably formaldehyde or acetaldehyde. |
申请公布号 |
US9056304(B2) |
申请公布日期 |
2015.06.16 |
申请号 |
US201113520083 |
申请日期 |
2011.01.19 |
申请人 |
JOHNSON MATTHEY FORMOX A.B. |
发明人 |
Andersson Arne;Haggblad Robert |
分类号 |
C07C45/38;B01J23/881;B01J23/887;B01J23/00;B01J35/00;B01J35/10;B01J37/03 |
主分类号 |
C07C45/38 |
代理机构 |
Young & Thompson |
代理人 |
Young & Thompson |
主权项 |
1. A catalyst, comprising:
iron, oxygen, and at least metal selected from the group consisting of vanadium and molybdenum, the catalyst having a spinel sructure, the catalyst being adapted by calcination for aldehyde production through selective oxidation of alkanol with oxygen. |
地址 |
Perstorp SE |