发明名称 Dyes for polymer coloration, their preparation and their use
摘要 The present invention relates to a compound of formula (I); The invention also relates to the preparation of the compound of formula (I) and to its use.
申请公布号 US9051468(B2) 申请公布日期 2015.06.09
申请号 US201213621330 申请日期 2012.09.17
申请人 Clariant International LTD 发明人 Barbieru Roxana;Görlitz Gunter;Harfmann Carsten
分类号 C07D401/02;C07D401/14;D06P3/00;C07D471/02;C07D471/08;C07D471/12;C09B5/62;C08K5/00 主分类号 C07D401/02
代理机构 Novak Druce Connolly Bove + Quigg LLP 代理人 Novak Druce Connolly Bove + Quigg LLP
主权项 1. A compound of the formula (1d), (1e), (1f), (1g) or (1h), wherein R11a and R12 each independently have one of the meanings of R11; R11 represent hydrogen, (C1-C35)-alkyl, singly or multiply oxygen-interrupted (C1-C35)-alkyl, aryl, aryl-(C1-C35)-alkyl, (C1-C35)-alkyl-aryl, aryloxy, (C1-C35)-alkoxy, monohydroxy-(C1-C35)-alkyl or polyhydroxy-(C2-C35)-alkyl and are each identical or different within a molecule of formula (I); q represents a number from 1 to 10; n represents a number from 0 to 10; A1a has one of the meanings of A3, independently of A3; and A3 represents (C5-C6)-cycloalkyl; heterocycloalkyl having 5 to 10 ring members; heteroaryl having 5 or 6 ring members; (C1-C35)-alkyl; (C2-C35)-alkyl interrupted by one or more hetero atoms, (C1-C35)-alkyl substituted by one or more substituents G2; (C2-C35)-alkyl interrupted by one or more hetero atoms and substituted by one or more substituents G2; G2 represents trifluoromethyl; cyclo-(C5-C6)-alkyl; aryl; heteroaryl having 5 or 6 ring members; heterocycloalkyl having 5 or 6 ring members; hydroxyl; (C1-C35)-alkoxy; aryloxy; (C2-C35)-acyl; arylcarbonyl, (C2-C35)-acyloxy; arylcarbonyloxy; (C2-C35)-acylamino; (C1-C35)-alkylsulfonylamino; aryl sulfonyl amino; arylcarbonylamino; carbamoyl; N-monocyclo-(C3-C8)-alkyl-carbamoyl; N-mono-(C1-C35)-alkyl-carbamoyl; N,N-dicyclo-(C3-C8)-alkyl-carbamoyl; N,N-di-(C1-C35)-alkyl-carbamoyl; N-monoaryl-carbamoyl; N,N-diaryl-carbamoyl; N-monocyclo-(C3-C8)-alkyl-N-monoarylcarbamoyl; N-mono-(C1-C35)-alkyl-N-monoaryl-carbamoyl; (C1-C35)-alkoxycarbonyl; aryloxycarbonyl; amino; monocyclo-(C3-C8)-alkyl-amino; mono-(C1-C35)-alkyl-amino; di(cyclo)-(C3-C8)-alkyl-amino; di-(C1-C35)-alkyl-amino; monoaryl-amino; diaryl-amino; monocyclo-(C3-C8)-alkylmonoarylamino; mono-(C1-C35)-alkylmonoaryl-amino; aminothiocarbonylamino; aminocarbonylamino; sulfamoyl; N-monocyclo-(C3-C8)-alkyl-sulfamoyl; N-mono-(C1-C35)-alkyl-sulfamoyl; N,N-dicyclo-(C3-C8)-alkyl-sulfamoyl; N,N-di-(C1-C35)-alkyl-sulfamoyl; N-monoaryl-sulfamoyl; N,N-diaryl-sulfamoyl; N-monocyclo-(C3-C8)-alkyl-N-monoarylsulfamoyl; N-mono-(C1-C35)-alkyl-N-monoarylsulfamoyl; aminosulfonyl-amino; (C1-C35)-alkylthio; arylthio; (C1-C35)-alkylsulfonyl or arylsulfonyl; wherein aryl represents a group of formula (9a) or (10a) wherein R18a to R24a each independently represent hydrogen; (C1-C12)-alkyl; trifluoromethyl; cyclo-(C3-C8)-alkyl; halogen; cyano; nitro; hydroxyl; (C1-C6)-alkoxy; (C2-C6)-acyl; (C2-C6)-acylamino; (C1-C6)-alkylsulfonylamino; carbamoyl; N-mono-(C1-C6)-alkyl-carbamoyl; N,N-di-(C1-C6)-alkyl-carbamoyl; amino; mono-(C1-C6)-alkyl-amino; di-(C1-C6)-alkyl-amino; aminocarbonylamino; sulfamoyl; N-mono-(C1-C6)-alkyl-sulfamoyl; N,N-di-(C1-C6)-alkyl-sulfamoyl; aminosulfonylamino; (C1-C6)-alkylthio or (C1-C6)-alkylsulfonyl; Q1a has one of the meanings of Q1, Q1 represents a group of formula (7) wherein r represents a rational number from 1 to 200; R15 and R16 each independently represent hydrogen, (C1-C35)-alkyl, singly or multiply oxygen-interrupted (C1-C35)-alkyl, aryl, aryloxy, (C1-C35)-alkoxy, monohydroxy-(C1-C35)-alkyl or polyhydroxy-(C2-C35)alkyl; wherein R11a and R12 each independently have one of the meanings of R11; q represents a number from 1 to 10; n represents a number from 0 to 10; A1b has one of the meanings of A4 independently of A4; and A4 represents a group Ar; Ar represents a group of formula (1) or (2) wherein R1 to R7 each independently represent hydrogen; (C1-C35)-alkyl; singly or multiply hetero atom-interrupted (C2-C35)-alkyl, monohydroxy-(C1-C35)-alkyl, polyhydroxy-(C2-C35)alkyl, vinylsulfonyl, hydroxyethylsulfonyl, trifluoromethyl; cyclo-(C5-C6)-alkyl; aryl; heteroaryl having 5 or 6 ring members; heterocycloalkyl having 5 or 6 ring members; halogen; cyano; nitro; hydroxyl; (C1-C35)-alkoxy; aryl-(C1-C35)-alkoxy, aryloxy; (C2-C35)-acyl; cyclo-(C3-C8)-alkylcarbonyl, arylcarbonyl, (C2-C35)-acyloxy; arylcarbonyloxy; (C2-C35)-acylamino; (C1-C35)-alkylsulfonylamino; arylsulfonylamino; arylcarbonylamino; carbamoyl; N-monocyclo-(C3-C8)-alkyl-carbamoyl; N-mono-(C1-C35)-alkyl-carbamoyl; N,N-dicyclo-(C3-C8)-alkyl-carbamoyl; N,N-di-(C1-C35)-alkyl-carbamoyl; N-monoaryl-carbamoyl; N,N-diaryl-carbamoyl; N-monocyclo-(C3-C8)-alkyl-N-monoarylcarbamoyl; N-mono-(C1-C35)-alkyl-N-monoarylcarbamoyl; (C1-C35)-alkoxycarbonyl; aryloxycarbonyl; amino; monocyclo-(C3-C8)-alkyl-amino; mono-(C1-C35)-alkyl-amino; di(cyclo)-(C3-C8)-alkyl-amino; amino; monoaryl-amino; diaryl-amino; monocyclo-(C3-C8)-alkylmonoarylamino; mono-(C1-C35)-alkylmonoaryl-amino; aminothiocarbonylamino; aminocarbonylamino; sulfamoyl; N-monocyclo-(C3-C8)-alkyl-sulfamoyl; N-mono-(C1-C35)-alkyl-sulfamoyl; N,N-dicyclo-(C3-C8)-alkyl-sulfamoyl; N,N-di-(C1-C35)-alkyl-sulfamoyl; N-monoaryl-sulfamoyl; N,N-diaryl-sulfamoyl; N-monocyclo-(C3-C8)-alkyl-N-monoarylsulfamoyl; N-mono-(C1-C35)-alkyl-N-monoarylsulfamoyl; aminosulfonylamino; (C1-C35)-alkylthio; arylthio; (C1-C35)-alkylsulfonyl or arylsulfonyl; or a substituent of formula (2) or (3) wherein R8 to R10 each independently represent (C5-C6)-cycloalkyl; heterocycloalkyl having 5 or 6 ring members; heteroaryl having 5 or 6 ring members; aryl; (C1-C35)-alkyl; (C2-C35)-alkyl interrupted by one or more hetero atoms; (C1-C35)-alkyl substituted by one or more substituents G1; or (C2-C35)-alkyl interrupted by one or more hetero atoms and substituted by one or more substituents G1; and R8 and R9 optionally represent hydrogen; Q1a has one of the meanings of Q1; wherein A1c represents a group of formula (4c) and A5 represents a group of formula (4d) wherein R11a, R12, R12a and R12b each independently have one of the meanings of R11; q, s and g each independently represent a number from 1 to 10; n represents a number from 0 to 10; T3 and T4 each independently represent hydrogen, (C1-C35)-alkyl, aryl, aryloxy, (C1-C35)-alkoxy or (C1-C35)-alkyl-aryloxy; Q1b and Q1c each have one of the meanings of Q1a independently of Q1a; and Q1a has one of the meanings of Q1; wherein R13 and R14 each independently have one of the meanings of R11a independently of R11a; t, w and z each independently represent a number from 0 to 10; Q2 and Q3 each independently have one of the meanings of Q1 independently of Q1; D represents a group of formula (8a) wherein R17a represents hydrogen or (C1-C35)-alkyl; and d, e and f independently represent a number from 0 to 5; A1a and A2a each independently have one of the meanings of A3 independently of A3; and A3 represents (C5-C6)-cycloalkyl; heterocycloalkyl having 5 to 10 ring members; heteroaryl having 5 or 6 ring members; (C1-C35)-alkyl; (C2-C35)-alkyl interrupted by one or more hetero atoms, (C1-C35)-alkyl substituted by one or more substituents G2; (C2-C35)-alkyl interrupted by one or more hetero atoms and substituted by one or more substituents G2; R11a has one of the meanings of R11; and Q1 is as defined above; wherein R13 and R14 each independently have one of the meanings of R11a independently of R11a; t, w and z each independently represent a number from 0 to 10; Q2 and Q3 each independently have one of the meanings of Q1 independently of Q1; D represents a group of formula (8a) wherein R17a represents hydrogen or (C1-C35)-alkyl; and d, e and f independently represent a number from 0 to 5; A1b and A2b each independently have one of the meanings of A4 independently of A4; and A4 represents a group Ar as defined above; R11a has one of the meanings of R11; and Q1 is as defined above.
地址 CH