发明名称 |
Method for producing epoxide |
摘要 |
A method for producing an epoxide is provided. The method includes a step of performing a reaction of an olefine compound and an oxidant to form the epoxide by using a titanium-silicon molecular sieve as a catalyst, thereby increasing the conversion rate of the oxidant and the yield of the epoxide. |
申请公布号 |
US9051287(B2) |
申请公布日期 |
2015.06.09 |
申请号 |
US201314065832 |
申请日期 |
2013.10.29 |
申请人 |
China Petrochemical Development Corporation |
发明人 |
Hsu Yu-Chuan;Hsieh Cheng-Fa |
分类号 |
C07D301/12;C07D301/03 |
主分类号 |
C07D301/12 |
代理机构 |
Mintz Levin Cohn Ferris Glovsky and Popeo, P.C. |
代理人 |
Mintz Levin Cohn Ferris Glovsky and Popeo, P.C. ;Corless Peter F.;Emmons Richard B. |
主权项 |
1. A method for producing an epoxide, comprising:
performing a reaction of an olefine compound and an oxidant in the presence of a solvent to form the epoxide by using a titanium-silicon molecular sieve of formula (I) as a catalyst:
(MxTiySi)Oz (I) wherein M is one selected from the group consisting of Ca, Sr and Ba; x is in a range from 0.0005 to 0.03, y is in a range from 0.005 to 0.06, y increases as x increases, and z is x+2y+2, wherein the catalyst is prepared by preparing a mixture of a silicon source, a titanium source, a source of an alkaline earth metal, a template and water; stirring the mixture to obtain a mixed gel and removing alcohol in the mixed gel; mixing a dispersion with the mixed gel; performing a hydrothermal treatment on the mixed gel containing the dispersion; and sintering the mixed gel. |
地址 |
Taipei TW |