发明名称 Method for producing epoxide
摘要 A method for producing an epoxide is provided. The method includes a step of performing a reaction of an olefine compound and an oxidant to form the epoxide by using a titanium-silicon molecular sieve as a catalyst, thereby increasing the conversion rate of the oxidant and the yield of the epoxide.
申请公布号 US9051287(B2) 申请公布日期 2015.06.09
申请号 US201314065832 申请日期 2013.10.29
申请人 China Petrochemical Development Corporation 发明人 Hsu Yu-Chuan;Hsieh Cheng-Fa
分类号 C07D301/12;C07D301/03 主分类号 C07D301/12
代理机构 Mintz Levin Cohn Ferris Glovsky and Popeo, P.C. 代理人 Mintz Levin Cohn Ferris Glovsky and Popeo, P.C. ;Corless Peter F.;Emmons Richard B.
主权项 1. A method for producing an epoxide, comprising: performing a reaction of an olefine compound and an oxidant in the presence of a solvent to form the epoxide by using a titanium-silicon molecular sieve of formula (I) as a catalyst: (MxTiySi)Oz  (I) wherein M is one selected from the group consisting of Ca, Sr and Ba; x is in a range from 0.0005 to 0.03, y is in a range from 0.005 to 0.06, y increases as x increases, and z is x+2y+2, wherein the catalyst is prepared by preparing a mixture of a silicon source, a titanium source, a source of an alkaline earth metal, a template and water; stirring the mixture to obtain a mixed gel and removing alcohol in the mixed gel; mixing a dispersion with the mixed gel; performing a hydrothermal treatment on the mixed gel containing the dispersion; and sintering the mixed gel.
地址 Taipei TW