| 摘要 |
A curable silicone composition comprises: (A) an organopolysiloxane represented by an average unit formula; (B) an organopolysiloxane having 10 or less silicon atoms, wherein 30 to 60 mole % of all silicon atom-bonded organic groups are alkenyl groups having from 2 to 6 carbons; (C) an organopolysiloxane represented by a general formula; (D) an organopolysiloxane having at least 2 silicon atom-bonded hydrogen atoms in a molecule, wherein the content of phenyl groups in all silicon atom-bonded organic groups in this component is 20 to 70 mole %; (E) an organopolysiloxane represented by an average unit formula; (F) a hydrosilylation reaction catalyst; (G) a white pigment; and (H) an inorganic filler other than a white pigment, has excellent formability for forming a cured product that has little discoloration and lowering of mechanical strength by heat and light, has high light reflectance, has excellent dimensional stability, and is capable of good attachment by a sealing agent used for an optical semiconductor device. |
| 主权项 |
1. A curable silicone composition comprising:
(A) 100 parts by mass of an organopolysiloxane represented by the following average unit formula:
(R13SiO1/2)a(R12SiO2/2)b(R1SiO3/2)c(SiO4/2)d(R2O1/2)e wherein R1 are independently the same or different, and are phenyl groups, alkyl groups having from 1 to 6 carbons, or alkenyl groups having from 2 to 6 carbons, provided that 30 to 80 mole% of all R1 are phenyl groups, and 5 to 20 mole% of all R1 are alkenyl groups; R2 is a hydrogen atom or alkyl group having from 1 to 6 carbons; and a, b, c, d, and e are numbers that respectively satisfy: 0≦a≦0.3, 0≦b≦0.7, 0.3 ≦c≦0.9, 0≦d≦0.1, 0≦e≦0.1, and a+b+c+d=1; (B) 5 to 50 parts by mass of an organopolysiloxane having 10 or less silicon atoms and not having a glycidoxyalkyl group or epoxycyclohexyl alkyl group, wherein 30 to 60 mole% of all silicon atom-bonded organic groups in the (B) component are alkenyl groups having from 2 to 6 carbons; (C) 0 to 40 parts by mass of an organopolysiloxane represented by the following general formula:
R33SiO(R32SiO)mSiR33 wherein R3 are independently the same or different, and are phenyl groups, alkyl groups having from 1 to 6 carbons, or alkenyl groups having from 2 to 6 carbons, provided that 30 to 70 mole% of all R3 are phenyl groups, and at least one R3 is an alkenyl group; and m is an integer in a range from 10 to 100; (D) an organopolysiloxane having at least 2 silicon atom-bonded hydrogen atoms in a molecule, wherein 20 to 70 mole% of all silicon atom-bonded organic groups in this component are phenyl groups, in an amount that provides 0.5 to 2.0 moles of silicon atom-bonded hydrogen atoms in the (D) component per 1 mole of the total amount of alkenyl groups in components (A) to (C) and component (E); (E) an organopolysiloxane represented by the following average unit formula:
(R43SiO1/2)f(R42SiO2/2)g(R4SiO3/2)h(SiO4/2)i(R5O1/2)j wherein R4 are independently the same or different, and are phenyl groups, alkyl groups having from 1 to 6 carbons, alkenyl groups having from 2 to 6 carbons, glycidoxyalkyl groups, or epoxycyclohexyl alkyl groups, provided that 15 to 60 mole% of all R4 are phenyl groups, 3 to 30 mole% of all R4 are alkenyl groups, and 5 to 30 mole% of all R4 are glycidoxyalkyl groups or epoxycyclohexyl alkyl groups; R5 is a hydrogen atom or an alkyl group having from 1 to 6 carbons; and f, g, h, i, and j are numbers that respectively satisfy: 0≦f≦0.5, 0≦g≦0.9, 0≦h≦0.7, 0≦i≦0.3, 0≦j≦0.02, and f+g+h+i =1, in an amount of 0.5 to 5.0 parts by mass per 100 parts by mass of the total amount of components (A) to (D); (F) a hydrosilylation reaction catalyst in an amount sufficient to accelerate a hydrosilylation reaction between the alkenyl groups in components (A) to (C) and component (E) and the silicon atom-bonded hydrogen atoms in component (D); (G) a white pigment in an amount of at least 25 parts by mass per 100 parts by mass of the total amount of components (A) to (F); and (H) an inorganic filler other than a white pigment in an amount of at least 40 parts by mass per 100 parts by mass of the total amount of components (A) to (F), wherein the content of the total amount of components (G) and (H) is not more than 300 parts by mass per 100 parts by mass of the total amount of components (A) to (F). |
