SOLVENTLESS PREPARATION OF ESTER-SUBSTITUTED DIARYL CARBONATES
摘要
<p>High yields of ester-substituted diary carbonates such as bis-methyl salicyl carbonate were obtained by the condensation of ester-substituted phenols with phosgene in the presence of a phase transfer catalyst (PTC) and optionally a tertiary amine catalyst in a solvent free reaction system comprising an aqueous phase held at a pH of 8.3 or higher. The optimized conditions of the present invention use an excess of ester-substituted phenol relative to phosgene and high conversion of phosgene to ester-substituted diaryl carbonate is observed. The product ester-substituted diaryl carbonate may be conveniently isolated as a solid by filtration or as a liquid in which the excess ester-substituted phenols serves as solvent. The method represents an attractive route for the manufacture of bis methyl salicyl carbonate and ester-substituted diaryl carbonates generally. The ester-substituted diaryl carbonates are useful for the preparation and modification of polycarbonates.</p>
申请公布号
EP1414779(B1)
申请公布日期
2015.05.27
申请号
EP20020742382
申请日期
2002.07.01
申请人
SABIC INNOVATIVE PLASTICS IP B.V.
发明人
BURNELL, TIMOTHY, BRYDON;MCCLOSKEY, PATRICK, JOSEPH;KAILASAM, GANESH;CELLA, JAMES, ANTHONY